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Possible differences between the surface and bulk structure of glasses

机译:玻璃的表面和整体结构之间可能存在差异

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摘要

Changes in cation co-ordination at glass surfaces (indicating an increase of the oxygen-to-cation ratio within the topmost superficial layers) are evidenced by comparing data acquired by spectroscopic techniques of different excitation depth. Based on these experimental results, a theoretical model is developed that predicts structural discrepancies between surface and bulk structure. Such reconstructed surfaces are of great importance for all kind of surface-related crystallization phenomena.
机译:通过比较不同激发深度的光谱技术获得的数据,可以证明玻璃表面阳离子配位的变化(表明最表层的氧与阳离子之比增加)。基于这些实验结果,建立了一个理论模型,该模型预测了表面和整体结构之间的结构差异。对于所有类型的与表面相关的结晶现象,这种重建的表面都非常重要。

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