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Mixing properties of X-Pb, (X = Cd, In) liquid binary alloys

机译:X-Pb(X = Cd,In)液态二元合金的混合性能

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摘要

We study the mixing properties of Cd-Pb and In-Pb segregating alloy systems using the Quasi-chemical approximation model (QCAM) within the framework of Quasi-lattice theory (QLT). The energetics of mixing in liquid binary alloys has been analyzed through the study of the various thermodynamic quantities. Positive deviation from Raoultian behavior was observed in the mixing properties of the alloys calculated. Our results are in good agreement with reported experimental data and support a weak demixing tendency in both Cd-Pb and In-Pb liquid alloys. (c) 2007 Elsevier B.V. All rights reserved.
机译:我们在准晶格理论(QLT)的框架内使用拟化学近似模型(QCAM)研究了Cd-Pb和In-Pb偏析合金体系的混合性能。通过研究各种热力学量,分析了液态二元合金中混合的能量。在计算合金的混合性能中观察到与拉乌尔蒂安行为的正偏差。我们的结果与报道的实验数据高度吻合,并支持Cd-Pb和In-Pb液态合金的弱混合趋势。 (c)2007 Elsevier B.V.保留所有权利。

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