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首页> 外文期刊>Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites >The presence of a thermally reversing window in Al-Te-Si glasses revealed by alternating differential scanning calorimetry and electrical switching studies
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The presence of a thermally reversing window in Al-Te-Si glasses revealed by alternating differential scanning calorimetry and electrical switching studies

机译:交替差示扫描量热法和电开关研究表明,Al-Te-Si玻璃中存在热反向窗口

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Alternating differential scanning calorimetric (ADSC) studies and electrical switching experiments have been undertaken on Al15Te85-xSix (2 <= x <= 12) system of glasses. These glasses are found to exhibit two crystallization reactions (T-c1 and T-c2), for compositions with x < 8. Above x = 8, a single-stage crystallization is seen. Further, a trough is seen in the composition dependence of non-reversing enthalpy (Delta H-NR), based on which it is proposed that there is a thermally reversing window in Al15Te85-xSix glasses, in the composition range 4 <= x <= 8. Electrical switching studies indicate that Al15Te85-xSix glasses exhibit a threshold type electrical switching at ON state currents less than 2 mA. Further, the switching voltages are found to increase with the increase in silicon content. It is interesting to note that the start (x = 4) and the end (x = 8) of the thermally reversing window are exemplified by a kink and a saturation in the composition dependence of switching voltages, respectively. (C) 2008 Elsevier B.V. All rights reserved.
机译:在Al15Te85-xSix(2 <= x <= 12)眼镜系统上进行了交替差示扫描量热(ADSC)研究和电气开关实验。对于x <8的组合物,发现这些玻璃表现出两个结晶反应(T-c1和T-c2)。在x = 8以上,观察到单阶段结晶。此外,在不可逆焓的组成依存关系(ΔH-NR)中看到一个低谷,据此提出在Al15Te85-xSix玻璃中存在一个热可逆窗口,其组成范围为4 <= x < =8。电气开关研究表明,Al15Te85-xSix玻璃在ON状态电流小于2 mA时显示阈值类型的电气开关。此外,发现开关电压随着硅含量的增加而增加。有趣的是,热反向窗口的起点(x = 4)和终点(x = 8)分别由开关电压的组成依赖性和纽结来举例说明。 (C)2008 Elsevier B.V.保留所有权利。

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