High lithium ion conduction of sulfide glass-based solid electrolytes and their application to all-solid-state batteries

Hayashi A; Minami K; Tatsumisago M

首页> 外文期刊>Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites >High lithium ion conduction of sulfide glass-based solid electrolytes and their application to all-solid-state batteries

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High lithium ion conduction of sulfide glass-based solid electrolytes and their application to all-solid-state batteries

机译：硫化物玻璃基固体电解质的高锂离子传导性及其在全固态电池中的应用

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Sulfide glass-based solid electrolytes prepared by melt quenching and mechanical milling were reviewed. The sulfide and oxysulfide glass-ceramic electrolytes in the system Li2S-P2S5-P2O5 with superionic Li7P3S11 and Li3.25P0.95S4 crystals exhibited high conductivity of over 10(-3) S cm(-1) at room temperature and high electrochemical stability. Newly designed all-sulfide batteries 80SnS.20P(2)S(5)/80Li(2)S.20P(2)S(5)/75Li(2)S.25Cu were successfully fabricated; reversible charge-discharge capacities of more than 400 mAh g(-1) were observed after the second to 10th cycles. The operation of those all-sulfide lithium secondary batteries is a first step for the realization of the all-solid-state monolithic batteries.

机译：综述了通过熔融淬火和机械研磨制备的基于硫化物玻璃的固体电解质。具有超离子Li7P3S11和Li3.25P0.95S4晶体的Li2S-P2S5-P2O5系统中的硫化物和氧硫化物玻璃陶瓷电解质在室温下显示出超过10（-3）S cm（-1）的高电导率和高电化学稳定性。成功设计了新设计的全硫化物电池80SnS.20P（2）S（5）/ 80Li（2）S.20P（2）S（5）/ 75Li（2）S.25Cu。在第二到第十个循环后，观察到可逆的充放电容量超过400 mAh g（-1）。这些全硫化锂二次电池的操作是实现全固态单块电池的第一步。

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《Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites》 |2009年第42期|共5页
作者
Hayashi A; Minami K; Tatsumisago M;
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正文语种 eng
中图分类非晶态和类晶态;
关键词
Mixed-anion effect; Fast ion conduction; Glass; Lithium battery; Electrolyte;

机译：混合阴离子效应;快速离子传导;玻璃;锂电池;电解质;

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1. High lithium ion conduction of sulfide glass-based solid electrolytes and their application to all-solid-state batteries [J] . Hayashi A, Minami K, Tatsumisago M Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2009,第37a42期

机译：硫化物玻璃基固体电解质的高锂离子传导性及其在全固态电池中的应用
2. Reactions at the electrode/electrolyte interface of all-solid-state lithium batteries incorporating Li-M (M = Sn, Si) alloy electrodes and sulfide-based solid electrolytes [J] . Sakuma Masamitsu, Suzuki Kota, Hirayama Masaaki, Solid state ionics . 2016,第Null期

机译：包含Li-M（M = Sn，Si）合金电极和基于硫化物的固体电解质的全固态锂电池在电极/电解质界面的反应
3. Bendable and Thin Sulfide Solid Electrolyte Film: A New Electrolyte Opportunity for Free-Standing and Stackable High-Energy All-Solid-State Lithium-Ion Batteries [J] . Nam Young Jin, Cho Sung-Ju, Oh Dae Yang, Nano letters . 2015,第5期

机译：可弯曲且薄的硫化物固体电解质膜：自由站立和可堆叠的高能量全固态锂离子电池的新电解质机会
4. Interfacial lithium-ion transfer reaction between graphite negative electrode and sulfide-based solid electrolyte in all-solid-state lithium secondary batteries [C] . Tomokazu Fukutsuka, Meiqi Huang, Kohei Miyazaki Annual World Conference on Carbon . 2015

机译：全固态锂二次电池中石墨负电极和硫醚固体电解质之间的界面锂离子转移反应
5. Investigation of Sulfide-based Solid Electrolytes for Sodium All-Solid-State Rechargeable Batteries [D] . Kompella, Christopher. 2017

机译：用于全固态可充电电池的硫化物基固体电解质的研究
6. Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery [O] . Atsushi Sakuda, Akitoshi Hayashi, Masahiro Tatsumisago -1

机译：具有良好机械性能的全固态锂电池硫化物固体电解质
7. Synthesis of Sulfide-based Solid Electrolytes for Application to All-Solid-State Lithium Sulfur Batteries [O] . Houtarde Diane 2016

机译：应用于全固态锂硫电池的基于硫化物的固体电解质的合成

High lithium ion conduction of sulfide glass-based solid electrolytes and their application to all-solid-state batteries

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