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Nd-doped phosphate glasses for high-energy/high-peak-power lasers

机译:掺钕磷酸盐玻璃,用于高能量/高峰值功率激光器

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摘要

The composition and properties of neodymium-doped (Nd-duped) phosphate glasses used for simultaneous high-energy (10(3)-10(6) J) and high-peak-power (10(12)-10(15) W) laser applications such as fusion energy research, are reviewed. The most common base glasses are meta-phosphates (O/P similar to 3) with the approximate composition: 60P(2)O(5)-10Al(2)O(3)-30M(2)O/MO; K/Ba or K/Mg are typical modifiers. The spectroscopy of Nd3+ in these glasses is well understood and laser properties can be accurately determined from measured spectroscopic properties. The major mechanisms for Nd3+ non-radiative relaxation are reviewed and empirical expressions are presented that predict these effects in phosphate glasses. Optical and thermal-mechanical properties have been measured on a number of laser glasses and can be correlated with composition. Sub-critical crack growth rates in stress regions I, II and III have been reported for the first time in phosphate laser grasses. The mechanism for Pt inclusion formation and dissolution has been studied leading to damage resistant (Pt-inclusion-free) laser glasses, (C) 2000 Elsevier Science B.V. All rights reserved. [References: 143]
机译:用于同时高能(10(3)-10(6)J)和高峰值功率(10(12)-10(15)W)的掺钕(Nd)磷酸盐玻璃的组成和性能)激光应用,如聚变能研究,进行了综述。最常见的基本玻璃是偏磷酸盐(O / P与3相似),其近似组成为:60P(2)O(5)-10Al(2)O(3)-30M(2)O / MO;钾/钡或钾/镁是典型的改性剂。这些玻璃中Nd3 +的光谱学已广为人知,并且可以从测得的光谱学性质中准确确定激光性质。审查了Nd3 +非辐射弛豫的主要机制,并提供了经验表达式来预测磷酸盐玻璃中的这些作用。光学和热机械性能已经在许多激光眼镜上进行了测量,并且可以与成分相关联。在磷酸盐激光草中首次报道了应力区域I,II和III中的亚临界裂纹生长速率。已经研究了导致Pt夹杂物形成和溶解的机理,从而导致了抗损伤(不含Pt的夹杂物)激光眼镜,(C)2000 Elsevier Science B.V.保留所有权利。 [参考:143]

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