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Diffusion in amorphous NiZrAl alloys

机译:非晶态NiZrAl合金中的扩散

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摘要

Tracer diffusion coefficients for large and small sized impurities were measured in the bulk metallic glass NixZryAlz for several compositions. Molecular beam deposition was employed to grow thin films and secondary ion mass spectrometry was used to determine the concentration-depth profiles of several tracers. A dependence of the atomic mobility of the tracer on its size was found, as observed in the binary NixZry amorphous alloy system. The presence of the Al reduces the diffusion coefficients in general, with a stronger decrease for the small sized tracer. The results support the existence of two different diffusion mechanisms proposed for amorphous metallic alloys. (C) 2000 Elsevier Science B.V. All rights reserved. [References: 15]
机译:在块状金属玻璃NixZryAlz中,针对几种成分,测量了大小杂质的示踪剂扩散系数。分子束沉积用于生长薄膜,二次离子质谱仪用于确定几种示踪剂的浓度-深度曲线。如在二元NixZry非晶态合金系统中所观察到的,发现了示踪剂原子迁移率与其大小的相关性。通常,Al的存在会降低扩散系数,而对于小尺寸的示踪剂而言,Al的降低幅度更大。结果支持存在两种针对非晶态金属合金的不同扩散机制。 (C)2000 Elsevier Science B.V.保留所有权利。 [参考:15]

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