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Column III and V elements as substitutional dopants in hydrogenated amorphous germanium

机译:III和V列元素在氢化非晶态锗中作为取代掺杂剂

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摘要

The doping properties of group III(B, Al, Ga, In) and V (N, P, As) impurities in a-Ge:H films deposited by rf sputtering were systematically studied. The Fermi level (E-F), band-gap (E-04), Urbach (E-0) tail energies, density of midgap defects, N,, and hydrogen content were determined as a function of the impurity concentration by standard methods. It was found that, for a constant amount of different dopant impurities, different E-F shifts are obtained, indicating different doping efficiencies. For Al, Ga, and In, the defect density displays a common behavior as a function of N-imp, N-D increasing linearly with N-imp for N-imp > 2 x 10(19) cm(-3). In contrast, for B and all group V elements a N-D alpha (N-imp)(1/2) relationship is found. These findings indicate that, for the case of p-type heavy metal doping of a-Ge:H, deep defects are induced by inactive impurities, whereas n-type doping appears to be consistent with a charge-induced bond breaking mechanism. A series of different doping-induced effects highlights the importance of the chemical aspects of substitutional doping in a-semiconductors. (C) 1998 Elsevier Science B.V. All rights reserved. [References: 16]
机译:系统研究了通过射频溅射沉积的a-Ge:H薄膜中的III族(B,Al,Ga,In)和V(N,P,As)杂质的掺杂性能。通过标准方法确定了费米能级(E-F),带隙(E-04),Urbach(E-0)尾能,中带隙缺陷密度,N和氢含量。已经发现,对于恒定量的不同掺杂剂杂质,获得了不同的E-F位移,这表明不同的掺杂效率。对于Al,Ga和In,缺陷密度显示出作为N-imp的函数的常见行为,对于N-imp> 2 x 10(19)cm(-3),N-D随N-imp线性增加。相反,对于B和所有V组元素,发现N-D alpha(N-imp)(1/2)关系。这些发现表明,对于a-Ge:H的p型重金属掺杂,由惰性杂质引起深缺陷,而n型掺杂似乎与电荷诱导的键断裂机理一致。一系列不同的掺杂诱导效应凸显了a型半导体中替代掺杂化学方面的重要性。 (C)1998 Elsevier Science B.V.保留所有权利。 [参考:16]

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