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Er3+ to glass matrix energy transfer in Ga-Ge-S : Er3+ system

机译:Ga-Ge-S:Er3 +系统中Er3 +到玻璃基质的能量转移

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Spectroscopic characteristics (spontaneous emission probabilities. radiative lifetimes, oscillator strengths, branching ratios and quantum efficiency) of Er3+ in Ga2S3-GeS2-Er2S3 glassy system are investigated by use of Judd-Ofelt theory. Lifetime measurements S-4(3/2) level of Er3+ in Ga2S3-GeS2-Er2S3 glasses with various Er3+ concentrations and optical gap energy are performed. Estimations of the non-radiative relaxation rate and the multiphonon relaxation rate demonstrate the occurrence of energy transfer from Er3+ ion to the electronic states of the glass matrix. The way of the practical application of this non-radiative energy transfer is suggested. (C) 2002 Elsevier Science B.V. All rights reserved. [References: 24]
机译:利用Judd-Ofelt理论研究了Ga2S3-GeS2-Er2S3玻璃态系统中Er3 +的光谱特征(自发发射概率,辐射寿命,振荡器强度,分支比和量子效率)。在具有不同Er3 +浓度和光隙能量的Ga2S3-GeS2-Er2S3玻璃中进行Er3 +的S-4(3/2)寿命测量。非辐射弛豫率和多声子弛豫率的估计表明发生了从Er3 +离子到玻璃基体电子态的能量转移。建议了这种非辐射能量转移的实际应用方式。 (C)2002 Elsevier Science B.V.保留所有权利。 [参考:24]

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