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Vibrational spectra, related properties, and structure of inorganic glasses

机译:无机玻璃的振动光谱,相关特性和结构

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摘要

Methods for the quantitative analysis of the IR and Raman spectra of various inorganic glasses to determine physically meaningful optical functions and individual band parameters are discussed. Available approaches to the problem of how to describe the mechanism of formation of the vibrational spectra of glasses (such as the quasi-molecular model, central force model and its recent refinements, and the model of phonon localization regions) are critically discussed. Recent data on band intensities and/or frequencies obtained with these methods for phosphate, borate, and germanate glasses are considered. Trends in the IR and Raman band assignments deduced from the current state of vibrational spectroscopy of glasses are analyzed and structural information obtained by different authors for binary phosphate, borate, and germanate glasses is compared. It is shown that, based on data on individual band parameters obtained, some related optical and dielectric properties of glasses in their transparency range can be calculated and/or modeled. Particular directions that are promising for further development of studies into vibrational spectroscopy of glasses are specified.
机译:讨论了各种无机玻璃的IR和拉曼光谱的定量分析方法,以确定物理上有意义的光学功能和各个波段参数。批判性地讨论了如何描述玻璃振动光谱形成机理的现有方法(如准分子模型,中心力模型及其最新的改进方法以及声子局域区域模型)。考虑了用这些方法获得的磷酸盐,硼酸盐和锗酸盐玻璃的带强度和/或频率的最新数据。分析了由玻璃的振动光谱的当前状态得出的红外和拉曼光谱带的分配趋势,并比较了不同作者针对二元磷酸盐,硼酸盐和锗酸盐玻璃获得的结构信息。结果表明,基于获得的各个波段参数的数据,可以计算和/或建模玻璃在其透明范围内的一些相关光学和介电特性。指出了有希望进一步发展玻璃振动光谱学研究的特定方向。

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