Structural investigations of the xZnCl(2)(3)(-(1-x)AlCl) glass-forming system: a Raman spectroscopic study

Kalampounias AG.; Yannopoulos SN.

首页> 外文期刊>Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites >Structural investigations of the xZnCl(2)(3)(-(1-x)AlCl) glass-forming system: a Raman spectroscopic study

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Structural investigations of the xZnCl(2)(3)(-(1-x)AlCl) glass-forming system: a Raman spectroscopic study

机译：xZnCl（2）（3）（-（1-x）AlCl）玻璃形成系统的结构研究：拉曼光谱研究

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We report on a temperature-dependence Raman scattering study of the binary glass-forming (halide) system xZnCl(2)-(1-x)AlCl3 for various compositions (x = 1, 0.9, 0.8, 0.6, 0.4, 0.2, 0.1, and 0 mol fraction). The elucidation of the structure of these glasses and liquids is attempted in order to clarify the structural modifications that the addition of AlCl3 brings about to the tetrahedral ZnCl2 structure. The analysis has shown that the vibrational modes of the mixtures arise from a superposition of the vibrational modes of the pure component salts. Emphasis is given on both the temperature-induced changes of the intermolecular and intramolecular vibrational modes. (C) 2003 Elsevier B.V. All rights reserved. [References: 7]

机译：我们报告了二元玻璃形成（卤化物）系统xZnCl（2）-（1-x）AlCl3对各种成分（x = 1、0.9、0.8、0.6、0.4、0.2、0.1的温度依赖性拉曼散射研究，和0摩尔分数）。试图阐明这些玻璃和液体的结构，以阐明添加AlCl3会导致四面体ZnCl2结构的结构修饰。分析表明，混合物的振动模式来自纯组分盐的振动模式的叠加。着重于温度引起的分子间和分子内振动模式的变化。（C）2003 Elsevier B.V.保留所有权利。 [参考：7]

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《Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites》 |2003年第0期|共6页
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Kalampounias AG.; Yannopoulos SN.;
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正文语种 eng
中图分类晶体学;
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Spectra;

机译：光谱;

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1. Structural investigations of the xZnCl(2)(3)(-(1-x)AlCl) glass-forming system: a Raman spectroscopic study [J] . Kalampounias AG., Yannopoulos SN. Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2003,第0期

机译：xZnCl（2）（3）（-（1-x）AlCl）玻璃形成系统的结构研究：拉曼光谱研究
2. Structural, Raman spectroscopic and microwave dielectric studies on (1-x) NiZrNb_2O_8-x ZnTa_2O_6 [J] . Mengjuan Wu, Yingchun Zhang, Maoqiao Xiang Journal of materials science . 2018,第17期

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3. A combined ~(77)Se NMR and Raman spectroscopic study of the structure of Ge _xSe _(1-x) glasses: Towards a self consistent structural model [J] . Edwards T.G., Sen S., Gjersing E.L. Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2012,第3期

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4. Composition-Dependent Structural and Raman Spectroscopic Studies on Y_(1-x)Ho_xCrO_3 (0≤x≤0.1) [C] . Ashish Kumar Mall, Ashish Garg, Rajeev Gupta DAE Solid State Physics Symposium . 2015

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5. Part I: Spectroscopic investigations of the heme active site coordination structure of the exogenous ligand-free myoglobin cavity mutant H93G and investigations of H93G-thiolate adducts as structural and mechanistic model systems for cytochrome P450. Part II: Spectroscopic investigations of proximal heme iron ligation in two novel halogenating and dehalogenating peroxidase enzymes isolated from marine sources. [D] . Roach, Mark Patrick. 1997

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机译：xTeO-（1-x）GeO（x = 0、0.2、0.4、0.6、0.8和1）碲酸盐玻璃的结构研究：依赖成分的拉曼光谱研究

Structural investigations of the xZnCl(2)(3)(-(1-x)AlCl) glass-forming system: a Raman spectroscopic study

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