Structure and vibrational modes of sulfur around the l-transition and the glass-transition

Kalampounias AG.; Kastrissios DT.; Yannopoulos SN.

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Structure and vibrational modes of sulfur around the l-transition and the glass-transition

机译：左旋转变和玻璃化转变周围硫的结构和振动模式

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In this paper we present a detailed temperature-dependence of Raman spectroscopic study of the vibrational modes of elemental sulfur around its polymerization transition or lambda-point (T-lambda) in order to elucidate the structural transformations. The considerable supercooling that liquid sulfur exhibits makes it possible to extend the light scattering study to similar to50 degreesC below melting point as well as to glassify sulfur by fast quenching the high temperature melt. Despite the apparent simplicity of sulfur, the determination of its structure has proved considerably puzzling. The results are discussed within the context of existing structural models for liquid sulfur. (C) 2003 Elsevier B.V. All rights reserved. [References: 14]

机译：在本文中，我们提出了有关元素硫在其聚合转变或λ点（T-lambda）周围的振动模式的拉曼光谱研究的详细温度依赖性，以阐明结构转变。液态硫表现出的相当大的过冷度使得可以将光散射研究扩展至熔点以下约50摄氏度，并可以通过快速淬火高温熔体来使硫玻璃化。尽管硫看起来很简单，但其结构的确定却令人费解。在现有的液态硫结构模型的背景下讨论了结果。（C）2003 Elsevier B.V.保留所有权利。 [参考：14]

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《Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites》 |2003年第0期|共5页
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Kalampounias AG.; Kastrissios DT.; Yannopoulos SN.;
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正文语种 eng
中图分类晶体学;
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Liquid sulfur; Polymerization transition; Raman-spectroscopy;

机译：液态硫聚合转变拉曼光谱;

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1. Structure and vibrational modes of sulfur around the l-transition and the glass-transition [J] . Kalampounias AG., Kastrissios DT., Yannopoulos SN. Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2003,第0期

机译：左旋转变和玻璃化转变周围硫的结构和振动模式
2. Computational tests of quantum chemical models for structures, vibrational frequencies, and heats of formation of molecules with phosphorus and sulfur atoms [J] . Hahn D.K., Raghuveer K.S., Ortiz J.V. The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2010,第31期

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3. The glassy and supercooled state of elemental sulfur: Vibrational modes, structure metastability, and polymer content [J] . Andrikopoulos K.S., Kalampounias A.G., Falagara O., The Journal of Chemical Physics . 2013,第12期

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4. Vibration of Straight and Curved Beam Coupled Systems: Proposal of a Simple Model for Side Structures of Railway Vehicle Carbodies to Analyse Their Elastic Vibrations [C] . Takahiro Tomioka IAVSD Symposium on Dynamics of Vehicles on Roads and Tracks . 2020

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5. Light scattering from acoustic vibrational modes in confined structures. [D] . Bandhu, Rudra Shyam. 2004

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6. Vibrational Spectral Analysis of Natisite (Na2TiSiO5) and its Structure Evolution in Water and Sulfuric Acid Solutions [O] . Fancheng Meng, Yahui Liu, Lina Wang, 2021

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7. Molecular Structures and Vibrational Spectra of Roesky’s Ketone, its Isomers and their Novel Sulfur and Selenium Analogues: An Insight using Density Functional Theory [O] . L. Rhyman, *P. Ramasami 2011

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8. Component Mode Synthesis and Large Deflection Vibration of Complex Structures. Volume 2:Single-Mode Large Deflection Vibrations of BEAMS and Plates Using Finite Element Method. Final Report,Period Ending January 31, 1987, [R] . mei, c. 1987

机译：复杂结构的分量模态综合与大挠度振动。第2卷：BEams和板的单模大挠度振动的有限元法。最终报告，截止日期为1987年1月31日，

Structure and vibrational modes of sulfur around the l-transition and the glass-transition

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