A multispectroscopic study of PbOxZnO0.6-x(P2O5)(0.4) glasses

Le Saout G.; Bessada C.; Simon P.; Blin A.; Vaills Y.; Fayon F.

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A multispectroscopic study of PbOxZnO0.6-x(P2O5)(0.4) glasses

机译：PbOxZnO0.6-x（P2O5）（0.4）玻璃的多光谱研究

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The structure of ternary PbOx-ZnO(0.6-x)-(P2O5)(0.4) glasses has been investigated using nuclear magnetic resonance (NMR), Raman scattering and infrared spectroscopy (IR), over the compositional range from x = 0 to 0.6. The evolution of the P-31 NMR chemical shift and Raman high-frequency modes reflects mainly the Zn/Pb substitution in these glasses. The NMR and Raman spectra show that at high ZnO content, the phosphate network has a strong interaction with Zn cations through P-O-Zn bonds. In glasses with high lead content, IR reflectivity spectra indicate that the phosphate network and lead cation are less correlated and that Pb 2(+) has a mixed network former-network modifier role in the glass structure. (C) 2001 Elsevier Science B.V. All rights reserved. [References: 27]

机译：在x = 0至0.6的组成范围内，使用核磁共振（NMR），拉曼散射和红外光谱（IR）研究了三元PbOx-ZnO（0.6-x）-（P2O5）（0.4）玻璃的结构。 P-31 NMR化学位移和拉曼高频模式的演变主要反映了这些玻璃中的Zn / Pb取代。 NMR和拉曼光谱表明，在高ZnO含量下，磷酸盐网络通过P-O-Zn键与Zn阳离子具有强相互作用。在高铅含量的玻璃中，红外反射光谱表明，磷酸盐网络与铅阳离子之间的相关性较低，并且Pb 2（+）在玻璃结构中具有混合的网络前网络改性剂作用。（C）2001 Elsevier Science B.V.保留所有权利。 [参考：27]

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《Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites》 |2001年第0期|共6页
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Le Saout G.; Bessada C.; Simon P.; Blin A.; Vaills Y.; Fayon F.;
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1. A multispectroscopic study of PbOxZnO0.6-x(P2O5)(0.4) glasses [J] . Le Saout G., Bessada C., Simon P., Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2001,第0期

机译：PbOxZnO0.6-x（P2O5）（0.4）玻璃的多光谱研究
2. Novel sol–gel preparation of (P2O5)0.4–(CaO)0.25–(Na2O)X–(TiO2)(0.35−X) bioresorbable glasses (X = 0.05, 0.1, and 0.15) [J] . Farzad Foroutan, Nora H. Leeuw, Richard A. Martin, Journal of Sol-Gel Science and Technology . 2015,第2期

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3. Raman and infrared structural investigation of (PbO)(x)(ZnO)((0.6-x))(P2O5)(0.4) glasses [J] . Le Saout Gwenn, Simon Patrick, Fayon Franck, Journal of Raman Spectroscopy: An International Journal for Original Work in All Aspects of Raman Spectroscopy, Including Higher Order Processes, and Also Brillouin- and Rayleigh Scattering . 2009,第5期

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4. Structural Studies of Na2O-Al2O3-SiO2-P2O5 Phosphate Glasses by Raman Spectroscopy [C] . The 12th Asian Pacific Confederation of Chemical Engineering Congress(第十二届亚太化工联盟大会暨化工展览会)论文集 . 2008

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6. DC and AC Conductivity Biosolubility and Thermal Properties of Mg-Doped Na2O–CaO–P2O5 Glasses [O] . Natalia Anna Wójcik, Sharafat Ali, Jakub Lech Karczewski, 2021

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机译：（P2O5）0.4–（CaO）0.25–（Na2O）X–（TiO2）（0.35-X）生物可吸收玻璃的新型溶胶-凝胶制备（X = 0.05、0.1和0.15）

A multispectroscopic study of PbOxZnO0.6-x(P2O5)(0.4) glasses

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