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Hydrophilic nature of silicate glass surfaces as a function of exposure condition

机译:硅酸盐玻璃表面的亲水性质与暴露条件的关系

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摘要

The work presented compares the hydrophilic nature of fused silica, BK-7 and soda time silicate (SLS) glass surfaces as a function of exposure conditions. Oxygen (O-2) plasma, water (H2O) plasma and a combination treatment of ultraviolet (UV) radiation (340 nm, 0.4 W/m(2)) in an aqueous environment (UV/HO) were used as the exposure treatments. The hydrophilic character of the surfaces was based on Fourier transform infrared reflectance studies (4000-3000 cm(-1) region) and contact angle analysis. It was found that the SLS glass was equally affected by all three exposure conditions, at least to the penetration depth of the IR reflection analysis (84degrees to the normal). A more hydrophilic behavior was achieved for fused silica and BK-7 using either the UV/H2O treatment or the H2O plasma treatment. It was confirmed by IR analysis that the O-2 plasma treatment of fused silica and BK-7 glass resulted in free silanol groups at the surface, which contributed to the lower hydrophilicity after treatment. (C) 2003 Elsevier B.V. All rights reserved. [References: 64]
机译:提出的工作比较了熔融二氧化硅,BK-7和苏打时间硅酸盐(SLS)玻璃表面的亲水性随暴露条件的变化。氧气(O-2)等离子体,水(H2O)等离子体和在水环境(UV / HO)中进行的紫外线(UV)辐射(340 nm,0.4 W / m(2))的组合处理被用作曝光处理。表面的亲水特性基于傅立叶变换红外反射研究(4000-3000 cm(-1)区域)和接触角分析。发现SLS玻璃在所有三种曝光条件下均受到相同的影响,至少在红外反射分析的穿透深度(与法线成84度)上均受到同样的影响。使用UV / H2O处理或H2O等离子处理,对于熔融二氧化硅和BK-7而言,具有更亲水的性能。通过IR分析证实,对熔融二氧化硅和BK-7玻璃进行O-2等离子体处理会在表面产生游离的硅烷醇基,这导致处理后的亲水性降低。 (C)2003 Elsevier B.V.保留所有权利。 [参考:64]

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