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Crystallization processes in amorphous Zr54CU46 alloy

机译:Zr54CU46非晶态合金的结晶过程

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The crystallization of amorphous Zr54Cu46 alloy was investigated by using X-ray diffraction (XRD), differential scanning calorimetry (DSC) and transmission electron microscopy (TEM) techniques. The experimental results show that an endothermic peak in DSC traces for amorphous Zr54Cu46 alloy exists at about 1006 K, indicating following eutectoid reaction occurs. namely, Cu10Zr7 + CuZr2 <----> CuZr in amorphous Zr54Cu46 alloy during heating. With increasing the heating rate, the glass transition temperature 1, and onset crystallization temperature T-g of amorphous Zr54Cu46 alloy increase in parallel, and the supercooled liquid region DeltaT(x) (= T-x - T-g) holds almost constant with an average value of 44 K. Both XRD and TEM results prove that Cu10Zr7 and CuZr2 are main crystallization products for amorphous Zr54Cu46 alloy under continuous heating conditions. No CuZr phase is identified because of its small precipitation amount. Finally, the crystallization processes of amorphous Zr54Cu46 alloy were summarized. (C) 2002 Elsevier Science B.V. All rights reserved. [References: 17]
机译:利用X射线衍射(XRD),差示扫描量热法(DSC)和透射电子显微镜(TEM)技术研究了非晶态Zr54Cu46合金的结晶。实验结果表明,非晶态Zr54Cu46合金的DSC曲线中的吸热峰存在于约1006 K处,表明发生了以下共析反应。即在加热过程中非晶Zr54Cu46合金中的Cu10Zr7 + CuZr2 <----> CuZr。随着加热速率的增加,非晶态Zr54Cu46合金的玻璃化转变温度1和起始结晶温度Tg平行增加,并且过冷液体区域DeltaT(x)(= Tx-Tg)几乎保持恒定,平均值为44 K XRD和TEM结果均证明Cu10Zr7和CuZr2是非晶Zr54Cu46合金在连续加热条件下的主要结晶产物。由于沉淀量小,未鉴定出CuZr相。最后,总结了非晶态Zr54Cu46合金的结晶过程。 (C)2002 Elsevier Science B.V.保留所有权利。 [参考:17]

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