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Microencapsulation of liquid and solid substances by reactive polymers

机译:反应性聚合物对液体和固体物质的微囊化

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This study is devoted to the development of techniques for the formation of polymeric microcapsules (MC) with either liquid or solid core and with the polymer shell containing diverse functional groups on the basis of new reactive functional copolymers (FC). Two approaches to the formation of MC containing FC shell that included the stages of "oil-in-water" or "water-in-oil" dispersion preparation followed by slow extraction of solvents from dispersed phase by dispersive media were examined. FC with the same structure was successfully applied for both "oil-in-water" and "water-in-oil" systems. Spherical MC with the liquid hydrocarbon core demonstrated essential increase in their volume after heating at the temperature exceeding a boiling point of hydrocarbon encapsulated. Presence of reactive groups in the MC shell opens up new opportunity for further tuning the MC properties via their interaction with proper compounds, particularly via graft-polymerisation of diverse vinyl monomers initiated from the MC surface.
机译:这项研究致力于发展形成具有液体或固体核以及在新的反应性功能共聚物(FC)的基础上聚合物壳包含各种官能团的聚合物微胶囊(MC)的技术。研究了两种形成含MC壳层的MC的方法,包括“水包油”或“油包水”分散液制备步骤,然后通过分散介质从分散相中缓慢萃取溶剂。具有相同结构的FC已成功应用于“水包油”和“油包水”系统。具有液态烃核的球形MC证明,在超过封装的烃沸点的温度下加热后,其体积必不可少的增加。 MC壳中反应性基团的存在为通过其与适当化合物的相互作用(尤其是通过从MC表面引发的各种乙烯基单体的接枝聚合)进一步调节MC性能提供了新的机会。

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