Spectral characterisation and electrochemical investigation of some divalent transition metal complexes of di(4-fluorophenyl)carbazone

A. H. M. Siddalingaiah; S. G. Naik; B. S. Sherigara; B. E. Kumara Swamy

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Spectral characterisation and electrochemical investigation of some divalent transition metal complexes of di(4-fluorophenyl)carbazone

机译：二（4-氟苯基）脲的二价过渡金属配合物的光谱表征和电化学研究

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The complexes of Co(II), Ni(II), Cu(II), Cd(II) and Pd(II) with di(4-fluorophenyl)carbazone (D4FPC) have been synthesised and characterised by elemental analyses, magnetic moment measurements, IR, ~1H NMR, UV-vis, and EPR spectral studies. The results show that D4FPC behaves as a bidentate monoanionic ligand coordinating through O and N donor atoms and forms 1:2 (metal-ligand) stoichiometry. The electrochemical reduction of Cu(II) complex has been studied on a glassy carbon electrode in non aqueous media using tetrabutylammonium perchlorate (Bu_4NClO_4) as a supporting electrolyte. The redox properties are discussed from the voltammetric measurements.

机译：合成了Co（II），Ni（II），Cu（II），Cd（II）和Pd（II）与二（4-氟苯基）脲（D4FPC）的配合物并通过元素分析，磁矩测量表征，IR，〜1H NMR，UV-vis和EPR光谱研究。结果表明，D4FPC表现为通过O和N供体原子配位的二齿单阴离子配体，并形成1：2（金属-配体）化学计量。已经在高水合四丁基铵（Bu_4NClO_4）作为支持电解质的非水介质中的玻璃碳电极上研究了Cu（II）配合物的电化学还原。从伏安法测量中讨论了氧化还原特性。

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《Journal of Molecular Structure. Theochem: Applications of Theoretical Chemistry to Organic, Inorganic and Biological Problems》 |2002年第3期|共7页
作者
A. H. M. Siddalingaiah; S. G. Naik; B. S. Sherigara; B. E. Kumara Swamy;
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正文语种 eng
中图分类结构化学;
关键词
spectral characterisation; substituted diphenylcarbazones; redox properties;

机译：光谱表征;取代的二苯基咔唑;氧化还原性质;

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1. Spectral characterisation and electrochemical investigation of some divalent transition metal complexes of di(4-fluorophenyl)carbazone [J] . A. H. M. Siddalingaiah, S. G. Naik, B. S. Sherigara, Journal of Molecular Structure. Theochem: Applications of Theoretical Chemistry to Organic, Inorganic and Biological Problems . 2002,第1a3期

机译：二（4-氟苯基）脲的二价过渡金属配合物的光谱表征和电化学研究
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Spectral characterisation and electrochemical investigation of some divalent transition metal complexes of di(4-fluorophenyl)carbazone

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