New catenary coordination polymers using fumarato ligand as bridging spacer: crystal structures of [Mn(phen)(2)(H2O)(2)]L center dot 4H(2)O, Mn(phen)(H2O)(2)L and Zn(phen)L center dot H2L with-H2L fumaric acid

Zheng YQ.; Lin JL.; Chen BY.

首页> 外文期刊>Journal of Molecular Structure >New catenary coordination polymers using fumarato ligand as bridging spacer: crystal structures of [Mn(phen)(2)(H2O)(2)]L center dot 4H(2)O, Mn(phen)(H2O)(2)L and Zn(phen)L center dot H2L with-H2L fumaric acid

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New catenary coordination polymers using fumarato ligand as bridging spacer: crystal structures of [Mn(phen)(2)(H2O)(2)]L center dot 4H(2)O, Mn(phen)(H2O)(2)L and Zn(phen)L center dot H2L with-H2L fumaric acid

机译：使用富马酸酯配体作为桥间隔基的新型链状配位聚合物：[Mn（phen）（2）（H2O）（2）] L中心点4H（2）O，Mn（phen）（H2O）（2）L和Zn（phen）L中心点H2L与-H2L富马酸

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Reactions of freshly precipitated MnCO3.xH(2)O and ZnCO3.yH(2)O with phen and fumaric acid (H2L) in EtOH/H2O afforded [Mn(phen)(2)(H2O)(2)]L.4H(2)O 1, Mn(phen)(H2O)(2)L 2 and Zn(phen)L.H2L 3, respectively. Compound 1 consists of [Mn(phen)(2)(H2O)(2)](2+) complex cations, fumarate anions and crystal H2O molecules. The complex cations are assembled by intermolecular pi-pi. stacking interactions into 2D layers, between which the fumarate anions and crystal H2O molecules form hydrogen bonded 2D open network. Within the complex 2, the [Mn(phen)(H2O)(2)](2+) moieties are bridged by bis-monodentate fumarato ligands to generate 1D zigzag chains, which are assembled into 2D layers by weak C-(HO)-O-... hydrogen bonds. The complex 3 is composed of fumaric molecules. and 1D zigzag (1)(infinity)[Zn(phen)L-2/(2)] polymeric chains resulting from the [Zn(phen)](2+) moieties interlinked by bis-monodentate fumarato ligands. The polymeric chains and fumaric molecules are held together via significant pi-pi stacking interactions between the fumaric plane and pendant phen to form 2D layers, which are further assembled by interlayer O-(HO)-O-... hydrogen bonds between hydroxyl group and non-coordinating fumarato 0 atom. (C) 2003 Elsevier Science B.V. All rights reserved. [References: 34]

机译：在EtOH / H2O中新鲜沉淀的MnCO3.xH（2）O和ZnCO3.yH（2）O与phen和富马酸（H2L）的反应得到[Mn（phen）（2）（H2O）（2）] L.4H （2）O 1分别是Mn（phen）（H2O）（2）L 2和Zn（phen）L.H2L 3。化合物1由[Mn（phen）（2）（H2O）（2）]（2+）络合阳离子，富马酸酯阴离子和晶体H2O分子组成。络合阳离子通过分子间pi-pi组装。堆叠相互作用成2D层，富马酸根阴离子和晶体H2O分子之间形成氢键2D开放网络。在配合物2中，[Mn（phen）（H2O）（2）]（2+）部分被双单齿富马酸酯配体桥接以生成1D之字形链，并通过弱C-（HO）将其组装成2D层-O -...氢键配合物3由富马酸分子组成。一维之字形（1）（无限）[Zn（phen）L-2 /（2）]聚合链，是由通过双单齿富马酸酯配体互连的[Zn（phen）]（2+）部分形成的。高分子链和富马酸分子通过富马酸平面与phen侧基之间显着的pi-pi堆积相互作用保持在一起，形成2D层，并通过层间O-（HO）-O -...羟基之间的氢键进一步组装和非配位的fumarato 0原子。（C）2003 Elsevier Science B.V.保留所有权利。 [参考：34]

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《Journal of Molecular Structure》 |2003年第3期|共9页
作者
Zheng YQ.; Lin JL.; Chen BY.;
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正文语种 eng
中图分类结构化学;
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Manganese; Zinc; Coordination polymers; Fumarato complexes; X-ray structures; Frameworks mil-n; Phen=1; 10-phenanthroline; Complexes; Succinate; Network; Dicarboxylate; Behavior; Odah(2); Adipate; Design;

机译：锰;锌;配位聚合物;烟酰胺络合物;X-射线结构;构架mil-n;Phen = 1;10-菲咯啉;络合物;琥珀酸酯;网络;二羧酸酯;行为;Odah（2）;己二酸酯;设计;

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1. New catenary coordination polymers using fumarato ligand as bridging spacer: crystal structures of [Mn(phen)(2)(H2O)(2)]L center dot 4H(2)O, Mn(phen)(H2O)(2)L and Zn(phen)L center dot H2L with-H2L fumaric acid [J] . Zheng YQ., Lin JL., Chen BY. Journal of Molecular Structure . 2003,第1a3期

机译：使用富马酸酯配体作为桥间隔基的新型链状配位聚合物：[Mn（phen）（2）（H2O）（2）] L中心点4H（2）O，Mn（phen）（H2O）（2）L和Zn（phen）L中心点H2L与-H2L富马酸
2. Synthesis and fungitoxic activity of manganese(II) complexes of fumaric acid: X-ray crystal structures of [Mn(fum)(bipy)(H2O)] and [Mn(Phen)(2)(H2O)(2)] (fum)center dot 4H(2)O (fumH(2) =fumaric acid; bipy=2,2 '-bipyridine; phen=1,10-phenanthroline) [J] . Devereux M., Leon V., Geraghty M., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2000,第10期

机译：富马酸锰（II）配合物的合成和杀真菌活性：[Mn（fum）（bipy）（H2O）]和[Mn（Phen）（2）（H2O）（2）]的X射线晶体结构）中心点4H（2）O（fumH（2）=富马酸; bipy = 2,2'-联吡啶; phen = 1,10-菲咯啉）
3. Two glutarato bridged coordination polymers: (1)(proportional to){[Mn(phen)](2)L-4/2} and (1)(proportional to){[Zn(phen)(H2O)]L-2/2}center dot H2O with H2L=glutaric acid [J] . Zheng YQ., Liu WH., Lin JL. Zeitschrift fur Anorganische und Allgemeine Chemie . 2002,第4期

机译：两种戊二酸桥联配位聚合物：（1）（与{{Mn（phen）]（2）L-4 / 2}成比例和（1）（与）{[Zn（phen）（H2O）] L-2成比例/ 2}中心点H2O，H2L =戊二酸
4. A Novel Chain-like Organic-Inorganic Hybrid Material: Hydrothermal Synthesis and Structureof H3N(CH2)4NH3 { Mn(phen)2(H2O)2Mn(phen)22MnMo12O24(HPO4)6(PO4)2(OH)6 }·4H2O [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：一种新型的链状有机-无机杂化材料：H3N（CH2）4NH3 {Mn（phen）2（H2O） 2 Mn（phen）2 2 MnMo12O24（HPO4）6（PO4）的水热合成和结构）2（OH）6}·4H2O
5. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of Mn(ph)(Phen)2(H2O)· 4H2O Mn(Phen)2(H2O)22(Isoph)2(Phen)· 12H2O and {Mn(Isoph)(bipy)4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 110-Phenanthroline; bipy = 22-Bipyridine) [O] . Michael Devereux, Malachy McCann, Vanessa Leon, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：Mn（ph）（Phen）2（H2O）·4H2OMn（Phen）2（H2O）2 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{Mn（Isoph）（bipy） 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 110-邻菲咯啉; bipy = 22 -联吡啶）
6. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of [Mn(ph)(Phen)2(H2O)]· 4H2O, [Mn(Phen)2(H2O)2]2(Isoph)2(Phen)· 12H2O and {[Mn(Isoph)(bipy)]4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 1,10-Phenanthroline; bipy = 2,2-Bipyridine) [O] . Devereux, Michael, McCann, Malachy, Leon, Vanessa, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：[Mn（ph）（Phen）2（H2O）]·4H2O，[Mn（Phen）2（H2O）2] 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{[Mn（Isoph）（bipy）] 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 1,10-邻菲咯啉; bipy = 2,2 -联吡啶）

New catenary coordination polymers using fumarato ligand as bridging spacer: crystal structures of [Mn(phen)(2)(H2O)(2)]L center dot 4H(2)O, Mn(phen)(H2O)(2)L and Zn(phen)L center dot H2L with-H2L fumaric acid

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