Evolution of 2, 3 '-bipyridine class of cyclometalating ligands as efficient phosphorescent iridium(III) emitters for applications in organic light emitting diodes

Reddy M. L. P.; Bejoymohandas K. S.

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Evolution of 2, 3 '-bipyridine class of cyclometalating ligands as efficient phosphorescent iridium(III) emitters for applications in organic light emitting diodes

机译：2，3'-联吡啶类环金属配体作为有机发光二极管中有效的磷光铱（III）发射体的演变

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Nowadays, the design and development of novel phosphorescent iridium(III) complexes for various optoelectronic applications is a well-recognized area of research. The fascinating photophysical properties of iridium(III) compounds are strongly influenced by the spin-orbit coupling exerted by the iridium(III) core, usually resulting in intense emissions with short excited-state lifetimes, which can be precisely controlled with the aid of molecular engineering of the chelating ligand. This review focuses on the recent developments and state of the art knowledge on phosphorescent iridium(III) compounds, especially on heteroleptic complexes derived from 2,3'-bipyridine class of cyclometalating and ancillary ligands, highlighting the excited state phenomenon behind their emission behavior. (C) 2016 Elsevier B.V. All rights reserved.

机译：如今，用于各种光电应用的新型磷光铱（III）配合物的设计和开发已成为公认的研究领域。铱（III）化合物的引人入胜的光物理性质受铱（III）核施加的自旋-轨道耦合的强烈影响，通常会导致强烈发射，激发态寿命短，可以借助分子精确控制螯合配体的工程。这篇综述着重于磷光铱（III）化合物的最新发展和最新知识，特别是衍生自2,3'-联吡啶类环金属化和辅助配体的杂配物，强调了其发射行为背后的激发态现象。（C）2016 Elsevier B.V.保留所有权利。

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《Journal of photochemistry and photobiology, C. Photochemistry reviews》 |2016年第null期|共19页
作者
Reddy M. L. P.; Bejoymohandas K. S.;
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正文语种 eng
中图分类光化学、辐射化学、超声波作用的化学过程;
关键词
Iridium complexes; Cyclometalating ligand; 2; 3 '-Bipyridine; Substituent effects; Structure-property relationships; Photophysical properties;

机译：铱配合物;环金属配体;2;3'-联吡啶;取代基效应;结构-性质关系;光物理性质;

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1. Evolution of 2, 3 '-bipyridine class of cyclometalating ligands as efficient phosphorescent iridium(III) emitters for applications in organic light emitting diodes [J] . Reddy M. L. P., Bejoymohandas K. S. Journal of photochemistry and photobiology, C. Photochemistry reviews . 2016,第Null期

机译：2，3'-联吡啶类环金属配体作为有机发光二极管中有效的磷光铱（III）发射体的演变
2. Iridium(III) complexes with cyclometalated styrylbenzoimidazole ligands:Synthesis, electrochemistry and as highly efficient emitters for organic light-emitting diodes [J] . Guanghui Zhang, Fang-Iy Wu, Xiaoqing Jiang, Synthetic Metals . 2010,第17a18期

机译：铱（III）与环金属化的苯乙烯基苯并咪唑配体的配合物：合成，电化学和有机发光二极管的高效发射体
3. A Yellow-Emitting Homoleptic Iridium(III) Complex Constructed from a Multifunctional Spiro Ligand for Highly Efficient Phosphorescent Organic Light-Emitting Diodes [J] . Ren Bao-Yi, Guo Run-Da, Zhong Dao-Kun, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2017,第14期

机译：黄色发射铱（III）复合物，由多功能螺旋配体构成，用于高效的磷光有机发光二极管
4. Highly efficient organic light-emitting diodes based on the red phosphorescent emitter sensitized by the green emitting iridium complex [C] . Ji Hyun Seo, Eun Young Choi, Jun Ho Kim, Nanoelectronics Conference (INEC), 2010 . 2010

机译：基于绿色发射铱络合物敏化的红色磷光发射体的高效有机发光二极管
5. Synthesis and photophysical characterization of phosphorescent cyclometalated iridium(III) complexes and their use in organic light emitting devices. [D] . Sajoto, Tissa. 2008

机译：磷光环金属化铱（III）配合物的合成和光物理表征及其在有机发光器件中的用途。
6. Phosphorescent cyclometalated complexes for efficient blue organic light-emitting diodes [O] . Yoshiyuki Suzuri, Tomohiro Oshiyama, Hiroto Ito, 2014

机译：用于高效蓝色有机发光二极管的磷光环金属化配合物
7. Blue-emitting cationic iridium(III) complexes featuring pyridylpyrimidine cyclometalating ligands and their use in sky-blue and blue-green light-emitting electrochemical cells (LEECs) and organic light-emitting diodes (OLEDs) [O] . Henwood, Adam Francis, Pal, Amlan Kumar, Cordes, David Bradford, 2017

机译：具有吡啶基嘧啶环金属化配体的发蓝光的阳离子铱（III）配合物及其在天蓝色和蓝绿色的发光电化学电池（LEEC）和有机发光二极管（OLED）中的用途

Evolution of 2, 3 '-bipyridine class of cyclometalating ligands as efficient phosphorescent iridium(III) emitters for applications in organic light emitting diodes

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