Photophysical behavior of transition metal complexes having interacting ligand localized and metal-to-ligand charge transfer states

Xian-yong Wang; Andre Del Guerzo; Russell H.S chmehl

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Photophysical behavior of transition metal complexes having interacting ligand localized and metal-to-ligand charge transfer states

机译：具有相互作用的配体局部化和金属到配体电荷转移态的过渡金属配合物的光物理行为

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Transition metal complexes having metal-to-ligand charge transfer (MLCT) excited states have been extensively investigated as sensitizers in light-induced electron transfer reactions. The photophysical behavior of the complexes is strongly dependent on the ligand serving as the electron acceptor. In systems where ligand localized triplet excited states are close in energy to the thermally equilibrated 3MLCT state, strong interaction between the states is observed. This article provides an overview of the unique photophysical behavior observed in systems of this type.

机译：具有金属至配体电荷转移（MLCT）激发态的过渡金属络合物已作为光敏电子转移反应中的敏化剂得到了广泛研究。配合物的光物理行为在很大程度上取决于用作电子受体的配体。在配体局部三线态激发态在能量上接近热平衡3MLCT态的系统中，观察到了这些态之间的强相互作用。本文提供了在此类系统中观察到的独特光物理行为的概述。

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《Journal of photochemistry and photobiology, C. Photochemistry reviews》 |2004年第1期|共23页
作者
Xian-yong Wang; Andre Del Guerzo; Russell H.S chmehl;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Metal-to-ligand charge transfer states; Intraligand; Aromatic hydrocarbon photophysics;

机译：金属到配体的电荷转移态配体芳烃光物理;

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1. Photophysical behavior of transition metal complexes having interacting ligand localized and metal-to-ligand charge transfer states [J] . Xian-yong Wang, Andre Del Guerzo, Russell H.S chmehl Journal of photochemistry and photobiology, C. Photochemistry reviews . 2004,第1期

机译：具有相互作用的配体局部化和金属到配体电荷转移态的过渡金属配合物的光物理行为
2. Switching between ligand-to-ligand charge-transfer, intraligand charge-transfer, and metal-to-ligand charge-transfer excited states in platinum(II) terpyridyl acetylide complexes induced by pH change and metal ions [J] . Han X, Wu LZ, Si G, Chemistry: A European journal . 2007,第26期

机译：pH值变化和金属离子诱导的铂（II）吡啶基乙炔化物络合物在配体到配体的电荷转移，配体内的电荷转移和金属到配体的电荷转移激发态之间切换
3. Switching between ligand-to-ligand charge-transfer, intraligand charge-transfer, and metal-to-ligand charge-transfer excited states in platinum(II) terpyridyl acetylide complexes induced by pH change and metal ions [J] . Han X, Wu LZ, Si G, Chemistry: A European journal . 2007,第26期

机译：pH值变化和金属离子诱导的铂（II）吡啶基乙炔化物络合物在配体到配体的电荷转移，配体内的电荷转移和金属到配体的电荷转移激发态之间切换
4. Probing metal-to-ligand charge transfer transitions in ruthenium complexes by quantitative two-photon absorption spectroscopy [C] . Charles W. Stark, Matt Rammo, Juri Pahapill, Conference on organic photonic materials and devices . 2018

机译：用定量双光子吸收光谱法探测钌配合物中金属到配体的电荷转移跃迁
5. Towards the use of Adaptive Feedback Control Pulse Shaping to Probe and Control Reactivity of the Metal-to-Ligand Charge Transfer Excited State in Ruthenium(II) Bis-Terpyridine Complexes. [D] . Hewitt, Joshua Thomas. 2013

机译：致力于使用自适应反馈控制脉冲整形来探测和控制钌（II）双-三联吡啶配合物中金属到配体电荷转移激发态的反应性。
6. Electron delocalization in the S1 and T1 metal-to-ligand charge transfer states of trans-substituted metal quadruply bonded complexes [O] . Brian G. Alberding, Malcolm H. Chisholm, Judith C. Gallucci, 2011

机译：反式取代的四重金属配合物在S1和T1的金属到配体的电荷转移态中的电子离域
7. Reactivity of Transition-Metal Complexes in Excited States: CO Bond Coupling Reductive Elimination of a Ni(II) Complex Is Elicited by the Metal-to-Ligand Charge Transfer State [O] . -1

机译：过渡金属配合物在激发状态下的反应性：通过金属 - 配体电荷转移状态引发了Ni（II）复合物的Co键偶联消除Ni（II）复合物
8. Solvent Dependence of Metal-to-Ligand Charge-Transfer Transitions. Evidence for Initial Electron Localization in MLCT Excited States of 2,2'-Bipyridine Complexes of Ru(II) And Os(II) [R] . Kober, E. M., Sullivan, B. P., Meyer, T. J. 1983

机译：金属与配体电荷转移跃迁的溶剂依赖性。 Ru（II）和Os（II）2,2'-联吡啶配合物mLCT激发态初始电子定位的证据

Photophysical behavior of transition metal complexes having interacting ligand localized and metal-to-ligand charge transfer states

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