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首页> 外文期刊>Journal of Physics, D. Applied Physics: A Europhysics Journal >Charge transport through conducting organic poly(2-methoxy-5(2-ethylhexyloxy)-1,4-phenylenevinylene)
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Charge transport through conducting organic poly(2-methoxy-5(2-ethylhexyloxy)-1,4-phenylenevinylene)

机译:通过导电的有机聚(2-甲氧基-5(2-乙基己氧基)-1,4-亚苯基亚乙烯基)进行电荷传输

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摘要

Current-voltage ( J-V) characteristics of poly( 2-methoxy-5( 2-ethyhexyloxy)-1,4-phenylenevinylene)( MEH-PPV) have been studied in the hole-only devices ITO/PEDOT:PSS/MEH-PPV/Au, as a function of temperature from 300 to 98 K. Hole conduction in MEH-PPV has been well explained by an exponential trap-controlled drift model. In a considerable range of applied voltages, current obeys the power law J proportional to Vl+1, where l = T-c/T and T-c is the characteristic temperature of the exponential trap distribution. Assuming the effective density of states N-v = 2.7 x 10(18) cm(-3), the holes trap density ( H-b) and characteristic temperature ( T-c) have been calculated to be 1 x 10(18) cm(-3) and 550 K, respectively. As the voltage further increases current deviates and becomes smaller than J proportional to Vl+1. At low temperatures and sufficiently high-applied voltages, current follows the V-2 law. At higher temperatures slopes less than 2 of the log J-log V plots have been observed. The possible reasons for this behaviour are mentioned.
机译:在仅开孔的器件ITO / PEDOT:PSS / MEH-PPV中研究了聚(2-甲氧基-5(2-乙基己氧基)-1,4-亚苯基亚乙烯基)(MEH-PPV)的电流-电压(JV)特性/ Au,它是温度从300到98 K的函数。MEH-PPV中的空穴传导已经由指数陷阱控制的漂移模型很好地解释了。在相当大的施加电压范围内,电流遵循与Vl + 1成比例的幂定律J,其中l = T-c / T,T-c是指数陷阱分布的特征温度。假设状态的有效密度Nv = 2.7 x 10(18)cm(-3),则空穴陷阱密度(Hb)和特征温度(Tc)已计算为1 x 10(18)cm(-3),并且分别为550 K随着电压的进一步增加,电流偏离并且变得小于与Vl + 1成比例的J。在低温和足够高的施加电压下,电流遵循V-2律。在较高的温度下,观察到的斜率小于对数J-log V图的2个。提到了此行为的可能原因。

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