Adhesion behaviour of self-assembled alkanethiol monolayers on silver at different stages of growth

Sai TP; Raychaudhuri AK

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Adhesion behaviour of self-assembled alkanethiol monolayers on silver at different stages of growth

机译：自组装烷硫醇单分子层在不同生长阶段对银的粘附行为

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We studied the development of interfacial energy gamma of alkanethiol self- assembled monolayers on Ag/mica substrates by force-displacement spectroscopy using an atomic force microscope. Self-assembled monolayers of decanethiol [CH3 (CH2)(9)SH] and octadecanethiol [CH3 (CH2) 17SH] were studied. The growth of the monolayer as a function of time was studied by an ellipsometer for three different concentrations of decanethiol and octadecanethiol. The thiols led to well-ordered self- assembled monolayer that showed atomic resolution images by lateral force microscopy mode. The behaviour of. showed non-monotonic variation in stages of adsorption, which was more prominent for short chain length decanethiol. The. reached a limiting value of 12 mJ m(-2) for decanethiol and 7 mJ m(-2) for octadecanethiol.

机译：我们通过使用原子力显微镜的力-位移光谱研究了链烷硫醇自组装单层在Ag /云母基底上的界面能γ的发展。研究了癸烷硫醇[CH3（CH2）（9）SH]和十八烷硫醇[CH3（CH2）17SH]的自组装单层。对于三个不同浓度的癸烷硫醇和十八烷硫醇，通过椭偏仪研究了单层生长随时间的变化。硫醇导致排列整齐的自组装单分子层，该单分子层通过侧向力显微镜模式显示了原子分辨率的图像。的行为。在吸附阶段表现出非单调变化，这对于短链长癸硫醇更为突出。的。癸烷硫醇的极限值达到12 mJ m（-2），十八烷硫醇的极限值达到7 mJ m（-2）。

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《Journal of Physics, D. Applied Physics: A Europhysics Journal》 |2007年第10期|共8页
作者
Sai TP; Raychaudhuri AK;
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正文语种 eng
中图分类应用物理学;
关键词
ATOMIC-FORCE MICROSCOPE; DECANETHIOL; AU(111); FILMS; MECHANISMS; ADSORPTION; FRICTION; SURFACES; AG(111); PHASE;

机译：原子力显微镜;癸内醇;AU（111）;薄膜;机理;吸附;摩擦;表面;AG（111）;相;

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1. Adhesion behaviour of self-assembled alkanethiol monolayers on silver at different stages of growth [J] . Sai TP, Raychaudhuri AK Journal of Physics, D. Applied Physics: A Europhysics Journal . 2007,第10期

机译：自组装烷硫醇单分子层在不同生长阶段对银的粘附行为
2. Effect of chain length on the adhesion behaviour of n-alkanethiol self-assembled monolayers on Au(111): An atomic force microscopy study [J] . S. Subramanian, S. Sampath Pramana . 2005,第4期

机译：链长对正构烷硫醇自组装单分子膜在Au（111）上的粘附行为的影响：原子力显微镜研究
3. Effect of chain length on the adhesion behaviour of n-alkanethiol self-assembled monolayers on Au(1 1 1): An atomic force microscopy study [J] . S Sampath1, S Subramanian Pramana . 2005,第4期

机译：链长对正构烷硫醇自组装单分子膜在Au（1 1 1）上的粘附行为的影响：原子力显微镜研究
4. ADHESION AND INTERFACIAL FRICTION OF SELF-ASSEMBLED MONOLAYERS OF PHENYL-TERMINATED ALKANETHIOLS [C] . Yutao Yang, Andrew C. Jamison, David Barriet, Proceedingss of the 33rd annual meeting of the Adhesion Society, Inc. . 2010

机译：苯甲基链烷醇自组装单分子膜的粘附和界面摩擦
5. Scanning tunneling microscopy studies of growth medium & temperature dependent structural phases of alkanethiol self-assembled monolayers, reactive self-assembled monolayers, & flat gold nanoparticle/indium tin oxide substrates and a scanning surface photovoltage microscopy study for local mechanical stress characterization in complementary metal oxide semiconductor devices. [D] . Dahanayaka, Dahanayaka Liyanage Daminda Hemal. 2010

机译：烷烃硫醇自组装单分子层，反应性自组装单分子层，扁平金纳米颗粒/铟锡氧化物基质的生长介质和温度依赖性结构相的扫描隧道显微镜研究，以及互补金属氧化物中局部机械应力表征的扫描表面光电压显微镜研究半导体器件。
6. The influence of surface lubricity on the adhesion of Navicula perminuta and Ulva linza to alkanethiol self-assembled monolayers [O] . J Bowen, M.E Pettitt, K Kendall, 2007

机译：表面润滑性对Navicula perminuta和Ulva linza对烷硫醇自组装单层粘附的影响
7. Effect of chain length on the adhesion behaviour of n-alkanethiol self-assembled monolayers on Au(111): An atomic force microscopy study [O] . Subramanian S, Sampath S 2005

机译：链长对正构烷硫醇自组装单分子膜在Au（111）上的粘附行为的影响：原子力显微镜研究
8. Self-Assembled Monolayers of Alkanethiols on Gold: Monolayers Derived From Two Components with Alkane Chains of Different Lengths. [R] . Folkers, J. P., Laibinis, P. E., Whitesides, G. M. 1992

机译：在金上自组装的alkanethiols单层膜：由两种不同长度的烷烃链组成的单层膜。

Adhesion behaviour of self-assembled alkanethiol monolayers on silver at different stages of growth

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