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Dielectric behaviour of cobalt titanium oxide

机译:钴钛氧化物的介电行为

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The complex dielectric properties of CoTiO3 ceramics were investigated as functions of temperature (130 K <= T <= 430 K) and frequency (100 Hz <= f <= 100 kHz). Two thermally activated dielectric relaxations were observed. TiO2 addition and annealing treatments were used to modify the behaviour of these relaxations. It was found that the low-temperature relaxation can be greatly enhanced by the addition of TiO2. Annealing in N-2 at 800 degrees C for 2h eliminates the low-temperature relaxation but largely strengthens the high-temperature relaxation, whereas annealing in O-2 at 800 degrees C for 2h causes the opposite effects. It was suggested that the low-temperature relaxation can be related to the dipolar effect induced by charge-carrier hopping motions while the high-temperature relaxation might be ascribed to the defect dipolar polarization.
机译:研究了CoTiO3陶瓷的复介电性能,该温度是温度(130 K <= T <= 430 K)和频率(100 Hz <= f <= 100 kHz)的函数。观察到两个热激活的介电弛豫。 TiO 2的添加和退火处理被用来改变这些弛豫的行为。发现通过添加TiO 2可以大大增强低温松弛。在N-2中在800摄氏度下退火2h消除了低温弛豫,但在很大程度上增强了高温弛豫,而在O-2中在800摄氏度下退火2h则产生了相反的效果。有人认为,低温弛豫可能与电荷载流子跳跃运动引起的偶极效应有关,而高温弛豫可能归因于缺陷偶极极化。

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