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首页> 外文期刊>Journal of Physics, D. Applied Physics: A Europhysics Journal >Synthesis and electron transfer property of sulfhydryl-containing multi-walled carbon nanotube/gold nanoparticle heterojunctions
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Synthesis and electron transfer property of sulfhydryl-containing multi-walled carbon nanotube/gold nanoparticle heterojunctions

机译:含巯基的多壁碳纳米管/金纳米粒子异质结的合成及电子转移性能

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摘要

One-dimensional metal/semiconductor heterojunction nanomaterials have opened many new opportunities for future nanodevices because of their novel structures and unique electrical and optical properties. In this work, sulfhydryl-containing multi-walled carbon nanotube/gold nanoparticle (MWCNT/Au) heterojunctions were synthesized in high yield by a sulfhydryl-functionalized self-assembly strategy. The component, size, structure, morphology and bond mode of the MWCNT/Au heterojunctions thus prepared were investigated and demonstrated by transmission electron microscopy, scanning electron microscopy, x-ray diffraction, energy-dispersive x-ray spectroscopy, Fourier-transform infrared and UV-visible measurements. Cyclic voltammogram and electrochemical impedance spectroscopy studies indicate that the MWCNT/Au heterojunctions have a novel electron transfer property, which retards electron transfer of the horseradish peroxidase or the ferricyanide in the underlying electrodes. We believe that MWCNT/Au heterojunctions with high stability and a unique electrical property are expected to find potential applications for nanodevices.
机译:一维金属/半导体异质结纳米材料因其新颖的结构以及独特的电学和光学特性,为未来的纳米器件打开了许多新机遇。在这项工作中,通过巯基官能化的自组装策略以高收率合成了含巯基的多壁碳纳米管/金纳米颗粒(MWCNT / Au)异质结。通过透射电子显微镜,扫描电子显微镜,X射线衍射,能量色散X射线光谱,傅立叶变换红外光谱和透射电子显微镜研究并证明了由此制备的MWCNT / Au异质结的成分,大小,结构,形态和键合模式。紫外线可见测量。循环伏安图和电化学阻抗谱研究表明,MWCNT / Au异质结具有新颖的电子转移特性,可阻止辣根过氧化物酶或铁氰化物在下面电极中的电子转移。我们相信,具有高稳定性和独特电性能的MWCNT / Au异质结有望在纳米器件中找到潜在的应用。

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