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首页> 外文期刊>Journal of Physics, D. Applied Physics: A Europhysics Journal >Magnetic and magnetocaloric properties of Ce_(1-x)R _xFe_2 and Ce(Fe_(1-x)M_x)_2 compounds
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Magnetic and magnetocaloric properties of Ce_(1-x)R _xFe_2 and Ce(Fe_(1-x)M_x)_2 compounds

机译:Ce_(1-x)R _xFe_2和Ce(Fe_(1-x)M_x)_2化合物的磁和磁热性质

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摘要

We have studied selected rare-earth doped and transition-metal doped CeFe_2 compounds by examining their structural, magnetic and magneto-thermal properties. With substitution of Ce by 5% and 10% Gd and 10% Ho, the Curie temperature can be tuned to the range 267-318 K. Localization of Ce 4f electronic state with rare earth substitutions is attributed for the enhancement of Curie temperature. On the other hand, with Ga and Al substitution at the Fe site, the system undergoes paramagnetic to ferromagnetic transition and then to an antiferromagnetic phase on cooling. The magnetocaloric effect across the transitions has been studied from both magnetization isotherms and heat capacity data. It is shown that by choosing the appropriate dopant and its concentration, the magnetocaloric effect around room temperature can be tuned.
机译:通过研究其结构,磁和磁热性质,我们研究了选择的稀土掺杂和过渡金属掺杂的CeFe_2化合物。用5%和10%的Gd和10%的Ho取代Ce可以将居里温度调节到267-318K。用稀土取代的Ce 4f电子态的局部化归因于居里温度的提高。另一方面,在Fe处用Ga和Al取代后,系统在冷却时经历顺磁性到铁磁性的转变,然后变成反铁磁性相。已从磁化等温线和热容数据研究了跨跃点的磁热效应。结果表明,通过选择合适的掺杂剂及其浓度,可以调节室温附近的磁热效应。

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