Synthesis and chirooptical properties of optically active poly(ester imide)s based on axially asymmetric 1,1 '-binaphthyls

Song NH; Qi W; Qiu XP; Gao LX; Ding MX

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Synthesis and chirooptical properties of optically active poly(ester imide)s based on axially asymmetric 1,1 '-binaphthyls

机译：基于轴向不对称的1,1'-联萘基的旋光性聚酰亚胺酯的合成及旋光性能

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A series of optically active poly(ester imide)s (PEsI's) has been synthesized by the polycondensation reactions of new axially asymmetric dianhydrides, that is, (R)-2,2'-bis(3,4-dicarboxybenzoyloxy)-1,1'-binaphthyl dianhydride and (S)-2,2'-bis(3,4-dicarboxybenzoyloxy)-1,1'-binaphthyl dianhydride, and various diamines with aromatic, semiaromatic, and aliphatic structures. The polymers have inherent viscosities of 0.45-0.70 dL/g, very good solubility in common organic solvents, glass-transition temperatures of 124-290 degreesC, and good thermal stability. Wide-angle X-ray crystallography of these polymers shows no crystal diffraction. In comparison with model compounds, an enhanced optical rotatory power has been observed for the repeat unit of optically active PEsI's based on aromatic diamines, and it has been attributed to a collaborative asymmetric perturbation of chiral 1,1'-binaphthyls along the rigid backbones. (C) 2004 Wiley Periodicals, Inc.

机译：通过新的轴向不对称二酐（R）-2,2'-双（3,4-二羧基苯甲酰氧基）-1的缩聚反应合成了一系列光学活性的聚（酯酰亚胺）（PEsI）。 1'-联萘二酐和（S）-2,2'-双（3,4-二羧基苯甲酰氧基）-1,1'-联萘二酐，以及各种具有芳族，半芳族和脂族结构的二胺。该聚合物的固有粘度为0.45-0.70 dL / g，在普通有机溶剂中的溶解度非常好，玻璃化转变温度为124-290℃，并且热稳定性良好。这些聚合物的广角X射线晶体学没有显示出晶体衍射。与模型化合物相比，已观察到基于芳族二胺的旋光性PEsI重复单元的旋光能力增强，这归因于手性1,1'-联萘沿刚性主链的协同不对称扰动。（C）2004年Wiley Periodicals，Inc.

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《Journal of Polymer Science, Part A. Polymer Chemistry》 |2004年第17期|共9页
作者
Song NH; Qi W; Qiu XP; Gao LX; Ding MX;
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正文语种 eng
中图分类高分子化合物工业（高聚物工业）;
关键词
axial asymmetry; 1; 1'-binaphthyl; chiral; polyimides; synthesis; LIQUID-CRYSTAL DISPLAYS; CHIRAL MACROMOLECULES; AROMATIC POLYIMIDES; GLASSY STATE; ENANTIOMERS; CHROMOPHORE; POLYMERS; FILMS; UNITS; TEMPERATURE;

机译：轴向不对称;1;1'-联萘;手性;聚酰亚胺;合成;液晶显示;手性大分子;芳族聚酰亚胺;玻璃态;对映体;铬;聚合物;薄膜;单位;温度;

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1. Synthesis and chirooptical properties of optically active poly(ester imide)s based on axially asymmetric 1,1 '-binaphthyls [J] . Song NH, Qi W, Qiu XP, Journal of Polymer Science, Part A. Polymer Chemistry . 2004,第17期

机译：基于轴向不对称的1,1'-联萘基的旋光性聚酰亚胺酯的合成及旋光性能
2. Synthesis and characterization of new thermally stable poly(ester-imide)s derived from 2,2'-bis(4-trimellitimidophenoxy)biphenyl and 2,2'-bis(4-trimellitimidophenoxy)-1,1'-binaphthyl and various aromatic dihydroxy compounds [J] . Hossein Behniafar, Sedigheh Habibian Polymer international . 2005,第8期

机译：由2,2'-双（4-三苯甲酰亚胺基苯氧基）联苯和2,2'-双（4-三苯甲酰亚胺基苯氧基）-1,1'-联萘和各种芳烃衍生的新型热稳定聚（酯酰亚胺）的合成与表征二羟基化合物
3. Electrically-Driven Chiroptical Switches Based on Axially Dissymmetric 1,1'-Binaphthyl and Electrochromic Viologens: Synthesis and Optical Properties [J] . Jian Deng, Naiheng Song, Qifeng Zhou, Organic letters . 2007,第26期

机译：基于轴向不对称的1,1'-联萘基和电致变色紫罗兰的电动按摩开关：合成和光学性质
4. Microstructure and properties of novel optically active poly(ester-imide)/TiO2 bionanocomposites containing natural amino acids moieties [C] . Mallakpour Shadpour 2010 International Conference on Enabling Science and Nanotechnology . 2010

机译：新型含天然氨基酸部分的旋光活性聚酯（酰亚胺）/ TiO 2 纳米复合材料的微观结构和性能
5. Asymmetric catalysis based on beta-aminoalcohols and 1,1'-binaphthyl derivatives. [D] . Mahmoud, Hussein Mahmoud. 2001

机译：基于β-氨基醇和1,1'-联萘基衍生物的不对称催化。
6. Synthesis and characterization of new optically active poly(azo-ester-imide)s via interfacial polycondensation [O] . Abdol R. Hajipour, Saeed Zahmatkesh, Parniyan Roosta, -1

机译：界面缩聚法合成新型光学活性聚（偶氮-酯-酰亚胺）
7. Electrically-Driven Chiroptical Switches Based on Axially Dissymmetric 1,1-Binaphthyl and Electrochromic Viologens: Synthesis and Optical Properties [O] . -1

机译：基于轴向不对称的1,1-二苯并基和电致变色的电致变色的电驱动的阴道开关：合成和光学性质
8. Novel Thermooxidatively Stable Poly(ether-imide-benzoxazole) and Poly (ester-imide-benzoxazole) [R] . Sundar, R. A., Mathias, L. J. 1994

机译：新型热氧化稳定的聚（醚 - 酰亚胺 - 苯并恶唑）和聚（酯 - 酰亚胺 - 苯并恶唑）

Synthesis and chirooptical properties of optically active poly(ester imide)s based on axially asymmetric 1,1 '-binaphthyls

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