Room temperature ionic liquid diluent for the extraction of Eu(III) using TRUEX extractants

Rout A.; Venkatesan K.A.; Srinivasan T.G.; Vasudeva Rao P.R.

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Room temperature ionic liquid diluent for the extraction of Eu(III) using TRUEX extractants

机译：室温离子液体稀释剂，用于使用TRUEX萃取剂萃取Eu（III）

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Extraction of europium(III) from nitric acid medium by a solution of tri-n-butylphosphate (TBP) and n-octyl(phenyl)-N,N- diisobutylcarbamoylmethylphosphine oxide (CMPO) in the room temperature ionic liquid, 1-alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (amimNTf2 where a = butyl or hexyl or octyl), was studied. The distribution ratio of ~((152+154))Eu(III) in TBP-CMPO/bmimNTf _2 was measured as a function of various parameters such as the concentrations of nitric acid, CMPO and NaNO_3. Remarkably large distribution ratios were observed for the extraction of europium(III) when bmimNTf_2 acted as diluent. The stoichiometry of metal-solvate in organic phase was determined by the slope analysis of extraction data.

机译：在室温离子液体1-烷基-溶液中，通过磷酸三正丁酯（TBP）和正辛基（苯基）-N，N-二异丁基氨基甲酰基甲基氧化膦（CMPO）的溶液从硝酸介质中萃取euro（III）。研究了3-甲基咪唑双（三氟甲磺酰基）酰亚胺（amimNTf2，其中a =丁基或己基或辛基）。测量TBP-CMPO / bmimNTf _2中〜（（152 + 154））Eu（III）的分布比率，该比率是各种参数（例如硝酸，CMPO和NaNO_3）的函数。当bmimNTf_2用作稀释剂时，observed（III）的提取率分布非常大。通过提取数据的斜率分析确定有机相中金属溶剂化物的化学计量。

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《Journal of Radioanalytical and Nuclear Chemistry: An International Journal Dealing with All Aspects and Applications of Nuclear Chemistry》 |2011年第1期|共5页
作者
Rout A.; Venkatesan K.A.; Srinivasan T.G.; Vasudeva Rao P.R.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Americium; Distribution ratio; Europium; N-diisobutylcarbamoylmethylphosphine oxide; n-Octyl(phenyl)-N; Room temperature ionic liquid; tri n-Butylphosphate;

机译：meric;分配比;Euro;N-二异丁基氨基甲酰基甲基氧化膦;正辛基（苯基）-N;室温离子液体;磷酸三正丁酯;

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1. Room temperature ionic liquid diluent for the extraction of Eu(III) using TRUEX extractants [J] . Rout A., Venkatesan K.A., Srinivasan T.G., Journal of Radioanalytical and Nuclear Chemistry: An International Journal Dealing with All Aspects and Applications of Nuclear Chemistry . 2011,第1期

机译：室温离子液体稀释剂，用于使用TRUEX萃取剂萃取Eu（III）
2. Ionic liquid extractants in molecular diluents: Extraction behavior of europium (HI) in quaternary ammonium-based ionic liquids [J] . Alok Rout, K.A. Venkatesan, T.G. Srinivasan Separation and Purification Technology . 2012,第Null期

机译：分子稀释剂中的离子液体萃取剂：（在基于季铵盐的离子液体中的萃取行为
3. Extraction of americium(III) from nitric acid medium by CMPO-TBP extractants in ionic liquid diluent [J] . Rout A, Venkatesan KA, Srinivasan TG, Radiochimica Acta: International Journal for Chemical Aspects of Nuclear Science and Technology . 2009,第12期

机译：CMPO-TBP萃取剂在离子液体稀释剂中从硝酸介质中萃取a（III）
4. ROOM-TEMPERATURE IONIC LIQUIDS AS DILUENTS FOR THE LIQUID-LIQUID EXTRACTION OF METAL IONS: PROMISE AND LIMITATIONS [C] . Mark L. Dietz, Mark P. Jensen, James V. Beitz, International Symposium on Hydrometallurgy . 2003

机译：室温离子液体作为金属离子液 - 液提取的稀释剂：承诺和限制
5. Anion effects in the extraction of metal ions into room-temperature ionic liquids (RTILs). [D] . Garvey, Sarah Lynn. 2013

机译：阴离子在将金属离子提取到室温离子液体（RTIL）中的作用。
6. Phosphonium ionic liquids as extractants for recovery of ruthenium(III) from acidic aqueous solutions [O] . Martyna Rzelewska, Monika Baczyńska, Maciej Wiśniewski, -1

机译：extract离子液体作为萃取剂用于从酸性水溶液中回收钌（III）
7. Solvent extraction of europium(III) to a fluorine-free ionic liquid phase with a diglycolamic acid extractant [O] . Rout Alok, Souza Ernesto Rezende, Binnemans Koen 2014

机译：用二乙醇酸萃取剂将extraction（III）溶剂萃取至无氟离子液相
8. Electrochemistry in Neutral Ambient-Temperature Ionic Liquids. 1. Studies of Iron (III), Neodymium (III), and Lithium(I) [R] . Lipsztajn, M., Osteryoung, R. A. 1985

机译：中性环境温度离子液体中的电化学。 1.铁（III），钕（III）和锂（I）的研究

Room temperature ionic liquid diluent for the extraction of Eu(III) using TRUEX extractants

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