...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Journal of Solid State Chemistry >Processing and characterization of new passive and active oxysulfide glasses in the Ge-Ga-Sb-S-O system
【24h】

Processing and characterization of new passive and active oxysulfide glasses in the Ge-Ga-Sb-S-O system

机译：Ge-Ga-Sb-S-O系统中新型被动和主动氧硫化玻璃的加工和表征

获取原文
获取原文并翻译 | 示例
   

获取外文期刊封面封底 >>

       
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

New passive and active oxysulfide glasses have been prepared in the Ge-Ga-Sb-S-O system employing a two-step melting process which involves the processing of the chalcogenide glass (ChG) and its subsequent melting with amorphous GeO2 or Sb2O3 powder. Optical characterization of the oxysulfide glasses has shown that the UV cut-off wavelength decreases with increasing oxygen content. Using Raman spectroscopy, correlations have been made between the formation of new Ge- and Sb-based oxysulfide structural units, the Sb content and the O/S ratio. We demonstrate the successful processing of active rare earth doped oxysulfide glasses by melting the chalcogenide glass with Er2O3 and Sb2O3 and also by melting the Er3+ doped chalcogenide glass with Sb2O3. Modification of the emission spectra at 1500 nm of Er3+ doped samples with the introduction of oxygen revealed that Er3+ most likely exists in dual O- and S-neighbor environments. Finally, the photo-response of these new glasses upon near-IR femtosecond laser irradiation has been investigated as a function of Sb content and O/S ratio and shows that the glasses are photo-sensitive to NIR fs laser light with the magnitude of the photo-sensitivity dependent on the glass' Sb content and O/S ratio. (C) 2009 Elsevier Inc. All rights reserved.
机译：已在Ge-Ga-Sb-S-O系统中采用两步熔化工艺制备了新的被动和主动氧硫化物玻璃，该工艺涉及硫族化物玻璃（ChG）的加工以及随后与无定形GeO2或Sb2O3粉末的熔化。氧硫化物玻璃的光学表征表明，紫外线截止波长随氧含量的增加而降低。使用拉曼光谱法，已经在新的基于Ge和Sb的氧硫化物结构单元的形成，Sb含量和O / S比之间建立了相关性。我们证明了通过用Er2O3和Sb2O3熔化硫族化物玻璃以及通过用Sb2O3熔化Er3 +掺杂硫族化物玻璃成功地处理了活性稀土掺杂的氧硫化物玻璃。掺入氧气对掺入Er3 +的样品在1500 nm处的发射光谱的修改表明，Er3 +最有可能存在于O和S邻域的双重环境中。最后，研究了这些新型眼镜在近红外飞秒激光辐照下的光响应，该光响应是Sb含量和O / S比的函数，表明这些眼镜对NIR fs激光的光敏感度为光敏度取决于玻璃的Sb含量和O / S比。 （C）2009 Elsevier Inc.保留所有权利。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号