CRYSTAL STRUCTURE OF [Co(N2C2H8)(3)][AuBr4](2)Br BIS(TETRABROMOAURATE(III))TRIS(ETHYLENEDIAMINE) COBALT(III) BROMIDE

Baidina IA; Makotchenko EV

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CRYSTAL STRUCTURE OF [Co(N2C2H8)(3)][AuBr4](2)Br BIS(TETRABROMOAURATE(III))TRIS(ETHYLENEDIAMINE) COBALT(III) BROMIDE

机译：[Co（N2C2H8）（3）] [AuBr4]（2）Br BIS（四溴金酸酯（III））三（乙二胺）钴（III）的晶体结构

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A double complex salt [Co(N2C2H8)(3)][AuBr4](2)Br is obtained and characterized using single crystal X-ray diffraction analysis. The crystallographic data of C6H24Au2Br9CoN6 are as follows: a = 21.6479(17) angstrom, b = 14.9085(12) angstrom, c = 8.2676(7) angstrom, beta = 110.820(2)degrees, V = 1538.92(12) angstrom(3), C2/c space group, Z = 4, d(x) = 3.602 g/cm(3). Square planar coordination of the gold atom in the complex anion is completed to a tetragonal pyramid by an additional bromine atom of the adjacent complex anion at the Au center dot center dot center dot Br distance of 3.677 angstrom.

机译：获得双络合物盐[Co（N2C2H8）（3）] [AuBr4]（2）Br，并使用单晶X射线衍射分析进行表征。 C6H24Au2Br9CoN6的晶体学数据如下：a = 21.6479（17）埃，b = 14.9085（12）埃，c = 8.2676（7）埃，beta = 110.820（2）度，V = 1538.92（12）埃（3）），C2 / c空间组，Z = 4，d（x）= 3.602 g / cm（3）。在Au中心点中心点中心点Br距离为3.677埃处，相邻阴离子中的另一个溴原子将络合物阴离子中金原子的方形平面配位完成为四棱锥。

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《Journal of structural chemistry》 |2010年第1期|共3页
作者
Baidina IA; Makotchenko EV;
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正文语种 eng
中图分类结构化学;
关键词
gold(III); cobalt(III); complexes; single crystal X-ray analysis;

机译：金（III）;钴（III）;配合物;单晶X射线分析;

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1. CRYSTAL STRUCTURE OF [Co(N2C2H8)(3)][AuBr4](2)Br BIS(TETRABROMOAURATE(III))TRIS(ETHYLENEDIAMINE) COBALT(III) BROMIDE [J] . Baidina IA, Makotchenko EV Journal of structural chemistry . 2010,第1期

机译：[Co（N2C2H8）（3）] [AuBr4]（2）Br BIS（四溴金酸酯（III））三（乙二胺）钴（III）的晶体结构
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6. DynamicNuclear Polarization of 1H 13C and 59Co in a Tris(ethylenediamine)cobalt(III)Crystalline Lattice Doped with Cr(III) [O] . Björn Corzilius, §, ⊥, -1

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CRYSTAL STRUCTURE OF [Co(N2C2H8)(3)][AuBr4](2)Br BIS(TETRABROMOAURATE(III))TRIS(ETHYLENEDIAMINE) COBALT(III) BROMIDE

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