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首页> 外文期刊>Journal of surface investigation: x-ray, synchrotron and neutron techniques >Mechanism for the formation of molecular clusters under ion sputtering
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Mechanism for the formation of molecular clusters under ion sputtering

机译:离子溅射下分子簇的形成机理

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摘要

The mechanism for the formation of molecular Si _nO _(2n+1) - clusters above the surface during the recombination of ions, atoms, and molecules independently sputtered in individual cascades is presented. Clusters form when sputtering products Si, O, SiO and SiO _2 (monomers) join the active anion O ~- successively as a result of pair collisions between them. The joining of monomers involves different combinations of them; in this case, the (Si _nO ~(2n+1)) ~- group is formed and consists of monomers with the same masses, but with different monomer compositions in the chain (combinatorial synthesis).
机译:提出了在单独的级联中独立溅射的离子,原子和分子重组期间在表面上方形成分子Si _nO _(2n + 1)-簇的机制。当溅射产物Si,O,SiO和SiO _2(单体)之间由于成对碰撞而依次加入活性阴离子O-时,会形成团簇。单体的连接涉及它们的不同组合。在这种情况下,形成(Si _nO〜(2n + 1))〜-基团,该基团由质量相同但链中单体组成不同的单体组成(组合合成)。

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