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首页> 外文期刊>Journal of surface investigation: x-ray, synchrotron and neutron techniques >Implementation of the regularization and cumulant techniques for interpreting and modeling analytical signals
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Implementation of the regularization and cumulant techniques for interpreting and modeling analytical signals

机译:实现用于解释和建模分析信号的正则化和累积技术

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摘要

A new approach to the modeling of analytical signals based on the combined Tikhonov regularization and cumulant analysis of random non-Gaussian processes, allowing us to subtract the background, determine and refine the parameters, and to separate overlapping peaks is presented. The efficiency of the developed procedure in analyzing the stripping voltammetric measurements of analytical signals for Cd(II), Cu(II), and Pb(II) pollutants of natural water at mercury-graphite electrodes is demonstrated.
机译:提出了一种基于Tikhonov正则化和随机非高斯过程的累积量分析相结合的分析信号建模的新方法,从而使我们能够减去背景,确定和优化参数以及分离重叠峰。证明了所开发程序在汞-石墨电极上分析天然水的Cd(II),Cu(II)和Pb(II)污染物的分析信号的溶出伏安法测量中的效率。

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