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首页> 外文期刊>Journal of surface investigation: x-ray, synchrotron and neutron techniques >Photoluminescence Quenching in Zinc Oxide Modified by Al_2O_3 and Al_2O_3 ? CeO_2 Nanopowders under Proton Irradiation
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Photoluminescence Quenching in Zinc Oxide Modified by Al_2O_3 and Al_2O_3 ? CeO_2 Nanopowders under Proton Irradiation

机译:Al_2O_3和Al_2O_3修饰的氧化锌中的光致发光猝灭。质子辐照下的CeO_2纳米粉

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摘要

The photoluminescence spectra of initial ZnO powder and that modified by Al_2O_3, Al_2O_3 ? CeO_2 nanopowders are investigated in the range 360-660 nm before and after 100-keV proton irradiation. It is found that the introduction of nanoparticles causes a decrease in the UV-band intensity and a change in the luminescence bands in the visual spectrum due to V_o~+ oxygen vacancies,O_(int)~- interstitial oxygen, and V_(Zn)~-zinc vacancies. Luminescence quenching in the UV and visible spectra occurs under the effect of protons. The decomposition of the spectra into elementary defects and analysis of changes in their integrated intensity during modification and irradiation of the powders are carried out.
机译:初始ZnO粉末和Al_2O_3,Al_2O_3?改性的发光光谱。在100keV质子辐照之前和之后,在360-660 nm范围内研究了CeO_2纳米粉。发现由于V_o〜+氧空位,O_(int)〜-间隙氧和V_(Zn)的引入,纳米粒子的引入引起了紫外光谱带强度的降低和可见光谱中发光带的变化。 〜-锌空位。紫外和可见光谱中的发光猝灭在质子的作用下发生。进行了将光谱分解为基本缺陷的过程,并对粉末的改性和辐照过程中其积分强度的变化进行了分析。

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