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首页> 外文期刊>Journal of surface investigation: x-ray, synchrotron and neutron techniques >Organic Ion Species Sputtered from Contaminated Water Ice by 1.5 MeV N~(2+) Ions
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Organic Ion Species Sputtered from Contaminated Water Ice by 1.5 MeV N~(2+) Ions

机译:1.5 MeV N〜(2+)离子从受污染的水冰中溅出的有机离子种类

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摘要

Electronic sputtering of organic species being mixed to water ice by residual-gas condensation is analyzed by secondary ion time-of-flight mass spectrometry. The ice samples were prepared at 15 K by deposition from a H_2O gas-flow and irradiated by 1.5 MeV N~(2+) ions while the temperature was raised up to 216 K. Desorption ion yields of positive H_2O specific ions as of some organic ion species are measured as a function of temperature. Remarkably high desorption yield variations, mainly of the C_nH_m~+ ions, were observed during the enrichment of organics hiding the emission of (H_2O)_nH_3O~+ cluster ions.
机译:通过二次离子飞行时间质谱分析了通过残留气体凝结混合到水冰中的有机物质的电子溅射。通过从H_2O气流中沉积在15 K下制备冰样品,并在温度升高至216 K的同时用1.5 MeV N〜(2+)离子辐照。正H_2O特定离子和某些有机物的解吸离子产率测量离子种类随温度的变化。在有机物富集过程中观察到明显高的解吸收率变化,主要是C_nH_m〜+离子,隐藏了(H_2O)_nH_3O〜+簇离子的发射。

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