A new class of macrocycle capable of binding exogenous metals: synthesis, structure, magnetic and electrochemical properties of a Cu(II) trinuclear complex based upon 1, 4, 8, 11-tetraaza-cyclotetradecane-2, 3-dione (exoO_2) cyclam

Leroy Cronin; Andrew R. Mount; Simon Parsons; Neil Robertson

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A new class of macrocycle capable of binding exogenous metals: synthesis, structure, magnetic and electrochemical properties of a Cu(II) trinuclear complex based upon 1, 4, 8, 11-tetraaza-cyclotetradecane-2, 3-dione (exoO_2) cyclam

机译：能够结合外源金属的新型大环化合物：基于1，4，8，11-四氮杂-环十四烷-2，3-二酮（exoO_2）环烷的Cu（II）三核配合物的合成，结构，磁性和电化学性质

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Synthesis of the new macrocycle 1, 4, 8, 11-tetraazacyclo-tetradecane-2, 3-dione [exoO_2] cyclam and its complexation with copper (II) salts results in the formation of a complex comprising two macrocycles each coordinated to a copper (II) ion via the tetraaza groups and linked together through a copper (II) ion coordinated to the exo-cis oxygen donors of each macrocycle.

机译：新大环1、4、8、11-四氮杂环-十四烷-2、3-二酮[exoO_2] cyclam的合成及其与铜（II）盐的络合导致形成包含两个大环的络合物，每个大环与一个铜配位（II）离子通过四氮杂基团并通过与每个大环的顺式-顺式供氧体配位的铜（II）离子连接在一起。

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《Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry》 |1999年第12期|共3页
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Leroy Cronin; Andrew R. Mount; Simon Parsons; Neil Robertson;
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1. A new class of macrocycle capable of binding exogenous metals: synthesis, structure, magnetic and electrochemical properties of a Cu(II) trinuclear complex based upon 1, 4, 8, 11-tetraaza-cyclotetradecane-2, 3-dione (exoO_2) cyclam [J] . Leroy Cronin, Andrew R. Mount, Simon Parsons, Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1999,第12期

机译：能够结合外源金属的新型大环化合物：基于1，4，8，11-四氮杂-环十四烷-2，3-二酮（exoO_2）环烷的Cu（II）三核配合物的合成，结构，磁性和电化学性质
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A new class of macrocycle capable of binding exogenous metals: synthesis, structure, magnetic and electrochemical properties of a Cu(II) trinuclear complex based upon 1, 4, 8, 11-tetraaza-cyclotetradecane-2, 3-dione (exoO_2) cyclam

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