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首页> 外文期刊>Journal of the Indian Chemical Society >A bimetallic dioxomolybdenum(VI) complex containing coordinated dihydrazone in staggered configuration
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A bimetallic dioxomolybdenum(VI) complex containing coordinated dihydrazone in staggered configuration

机译:双金属二氧钼钼(VI)络合物,其中包含配位错配的st

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摘要

The reaction between bis(acetylacetonato)dioxomolybdenum(VI) and bis(2-hydroxy-1-naphthaldehydr)malonoyldihydrazone yields homobimetallic complex [(MoO_2)_2(CH_2L)(H_2O)_2] in which dihydrazone coordinates to the metal centres in the staggered configuration. The complex undergoes a dynamic process in solution in which the dissociated form remains in equilibrium with the undissociated form.
机译:双(乙酰丙酮)二氧钼钼(VI)与双(2-羟基-1-萘二氢)丙二酰基二hydr反应生成均双金属络合物[(MoO_2)_2(CH_2L)(H_2O)_2],其中di di与错位的金属中心配位组态。络合物在溶液中经历动态过程,其中解离的形式与未解离的形式保持平衡。

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