Synthesis and crystal structure of cis-dioxomolybdenum(VI) complex with salicylaldehyde-2-pyrazinoylhydrazone

G.S.Sanyal; R.Ganguly; P.K.Nath; R.J.Butcher

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Synthesis and crystal structure of cis-dioxomolybdenum(VI) complex with salicylaldehyde-2-pyrazinoylhydrazone

机译：水杨醛-2-吡嗪酰基hydr的顺式-二氧钼钼（VI）配合物的合成和晶体结构

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MoO_2Cl_2(DMF)_2 reacts with salic ylaldehyde-2-pyrazinoylhydrazone (SAPH) in methanol to afford the title complex. X-Ray structure analysis reveals that the complex possesses the usual cis-MoO_2~(2+) moiety and SAPH behaves as a dianionic tridentate donor coordinating through azomethine nitrogen, enolic and phenolic oxygens. The sixth coordination site around Mo is occupied by a water molecule in the distorted octahedral geometry of the complex. The second water molecule is present as water of crystallization.

机译：MoO_2Cl_2（DMF）_2与水杨醛-2-吡嗪酰基hydr（SAPH）在甲醇中反应，得到标题配合物。 X射线结构分析表明该配合物具有通常的顺式MoO_2〜（2+）部分，SAPH表现为通过偶氮甲氮，烯醇和酚氧配位的三阴离子三齿供体。 Mo周围的第六个配位点被络合物扭曲的八面体几何结构中的水分子占据。第二水分子作为结晶水存在。

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《Journal of the Indian Chemical Society》 |2002年第6期|共3页
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G.S.Sanyal; R.Ganguly; P.K.Nath; R.J.Butcher;
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机译：水杨醛-2-吡嗪酰基hydr的顺式-二氧钼钼（VI）配合物的合成和晶体结构
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Synthesis and crystal structure of cis-dioxomolybdenum(VI) complex with salicylaldehyde-2-pyrazinoylhydrazone

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