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首页> 外文期刊>Journal of the Indian Chemical Society >Variation in stoichiometry and mechanism of some redox systems
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Variation in stoichiometry and mechanism of some redox systems

机译：一些氧化还原系统的化学计量和机理的变化

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2.Reduction of (S_2O_8~(2-) + Ag~I) system in acid solutions.Competence of intermediate SO_4~- to react with H_2O/substrate/Ag~I leading to a variation in the stoichiometry and mechanism.(a) Oxidation of Fe~(II) (b) Oxidation of Ce~(III) (c) Oxidation of hyponitrous acid (H_2N_2O_2) 3.Reactions of hydrazine in acid solutions.Competence of hydrazyl radical (N_2H_3) to get dimerized and decomposed/oxidised leading to a variation in the stoichiometry and mechanism.(a)Oxidation by Ce~(IV) (b)Oxidation by Tl~(III) 4.Reactions of hydroxylamine.Ratio of the initial reactant-concentrations deciding the stoichiometry and mechanism.Intermediates sensitive to light.(a)Oxidation by peroxomonophosphoric acid (H_3PO_5) in acid solutions (b)Oxidation by Tl~(III) in acid solutions (c)Oxidation by Fe~(III) in buffered solutions 5.Reactions of hyponitrous acid.Competence of intermediatee oxyhyponitrous acid (H_2N_2O_3) and HNO_2 to decompose/get oxidised leading to a variation in the stoichiometry and mechanism.(a)Oxidation by Tl~(III) in acid solutions (b)Oxidation by Ce~(IV) in acid solutions (c)Oxidation by iodine in buffered solutions (d)Oxidation by Fe(CN)_6~(3-) in alkaline solutions 6.Complicated analysis in a simple system of Tl~(III)-Sb~(III) in acid perchlorate solutions for 1 : 1 stoichiometry.
机译：（2）在酸性溶液中还原（S_2O_8〜（2-）+ Ag〜I）系统中间SO_4 ~~与H_2O /底物/ Ag〜I反应的能力导致化学计量和机理的变化。 Fe〜（II）的氧化（b）Ce〜（III）的氧化（c）次硝酸（H_2N_2O_2）的氧化3.酸溶液中肼的反应肼基（N_2H_3）的能力使其二聚，分解/氧化（a）Ce〜（IV）的氧化（b）Tl〜（III）的氧化4.羟胺的反应。初始反应物浓度的比值决定了化学计量和机理。中间体对光敏感。（a）在酸溶液中被过氧一磷酸（H_3PO_5）氧化（b）在酸溶液中被Tl〜（III）氧化（c）在缓冲溶液中被Fe〜（III）氧化5。中间氧次硝酸（H_2N_2O_3）和HNO_2分解/氧化的能力导致化学计量比和m的变化机理（a）在酸性溶液中被Tl〜（III）氧化（b）在酸性溶液中被Ce〜（IV）氧化（c）在缓冲溶液中碘的氧化（d）由Fe（CN）_6〜（3）的氧化-）在碱性溶液中6.在简单的Tl〜（III）-Sb〜（III）高氯酸溶液中进行复杂的分析，化学计量比为1：1。

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