Reactivity in the oxidation of benzyl ethers by W-bromonicotinamide in aqueous acetic acid medium

M. Balasubramaniyan; V. Priya; N. Mathiyalagan

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Reactivity in the oxidation of benzyl ethers by W-bromonicotinamide in aqueous acetic acid medium

机译：W-溴烟酰胺在含水乙酸介质中氧化苄基醚的反应性

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N-Bromonicotinamide (NBN) oxidation of benzyl ethers is investigated in aqueous acetic acid medium over the temperature range of 318-333 K. The reaction exhibits first order dependence on [NBN]. The order of reaction with respect to substrate is zero. It fails to induce polymerization of acrylonitrile under the experimental conditions employed. Arrhenius and activation parameters are evaluated. Effects of dielectric constant and ionic strength of the medium on the reaction rate have been studied. Oxidation products are identified. A suitable reaction scheme is proposed and an appropriate rate law is deduced to account for the observed kinetic data.

机译：在318-333 K的温度范围内，在乙酸水溶液中研究了苄基醚的N-溴烟酰胺（NBN）氧化。该反应对[NBN]表现出一级依赖性。相对于底物的反应顺序为零。在所采用的实验条件下，它不能引起丙烯腈的聚合。阿雷尼乌斯和激活参数进行了评估。研究了介质的介电常数和离子强度对反应速率的影响。确定了氧化产物。提出了合适的反应方案，并推导了合适的速率定律以解释所观察到的动力学数据。

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《Journal of the Indian Chemical Society》 |2010年第8期|共4页
作者
M. Balasubramaniyan; V. Priya; N. Mathiyalagan;
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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
N-Bromonicotinamide; benzyl ethers; kinetics; mechanism.;

机译：N-溴烟酰胺;苄基醚;动力学;机理;

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1. Reactivity in the oxidation of benzyl ethers by W-bromonicotinamide in aqueous acetic acid medium [J] . M. Balasubramaniyan, V. Priya, N. Mathiyalagan Journal of the Indian Chemical Society . 2010,第8期

机译：W-溴烟酰胺在含水乙酸介质中氧化苄基醚的反应性
2. Kinetics and mechanism of oxidation of benzyl phenyl ethers by N-cMoronieotinamide in aqueous acetic acid medium [J] . Priya V, Mathiyalagan N. Research Journal of Chemistry and Environment . 2012,第1期

机译：N-cMoronieotinamide在含水乙酸介质中氧化苄基苯基醚的动力学和机理
3. Kinetics and mechanism of oxidation of benzyl ethers by N-chloronicotinamide in aqueous acetic acid medium [J] . N. Mathiyalagan, V. Priya, J. John Bosco Journal of the Indian Chemical Society . 2009,第5期

机译：N-氯烟酰胺在乙酸水溶液中氧化苄基醚的动力学及机理
4. Oxidation of aniline and its derivatives by tert-butylhydroperoxide using meso-tetraphenylporphyriniron(iii) chloride as catalyst in aqueous acetic acid medium: Degradation kinetics [C] . R. Mayildurai, M. Raja, V. Akhileshuvar International Conference on Physics and Chemistry of Materials in Novel Engineering Applications . 2020

机译：使用Meso-Tetraphynylyriniron（III）作为乙酸水溶液中催化剂的叔丁基氧化盐氧化苯胺及其衍生物的氧化：降解动力学
5. A STUDY OF THE ACIDITY AND COMPLEXING PROPERTIES OF NITRILOTRIACETIC ACID N-OXIDE, ETHYLENE DIAMINETETRAACETIC ACID N,N'-DIOXIDE, DIPICOLINIC ACID N-OXIDE, AND 8-HYDROXYQUINOLINE-5-SULFONIC ACID N-OXIDE IN AQUEOUS SOLUTION. [D] . FREYER, LARRY EUGENE. 1975

机译：水溶液中亚硝基三乙酸N-氧化物，乙烯二胺基乙酸N，N'-二氧化物，双吡啶甲酸N-氧化物和8-羟基喹啉-5-磺酸磺酸的酸及其络合性能的研究。
6. Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study [O] . P. Giridhar Reddy, K. Ramesh, S. Shylaja, 2012

机译：N-溴代琥珀酰亚胺在乙酸水溶液中Ru（III）催化脂肪族酮的氧化动力学研究
7. Kinetics and mechanism of the selective oxidation of benzyl alcohols by acidified dichromate in aqueous acetic acid medium [O] . K Bijudas 2014

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Reactivity in the oxidation of benzyl ethers by W-bromonicotinamide in aqueous acetic acid medium

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