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首页> 外文期刊>Journal of the Indian Chemical Society >Photochemical intramolecular cyclization routes to heterocycles
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Photochemical intramolecular cyclization routes to heterocycles

机译:光化学分子内环化途径形成杂环

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摘要

1-Aryl-3-(2-azidoaryl)prop-2-en-1-ones have been prepared from o-nitro aromatic aldehydes. The 2-aroylindole derivatives are easily prepared from these derivatives in a tandem reaction sequence in moderate yields. Photolytic process is found to be much more facile than the thermal process in this transformation. Naphthofuran derivatives have been prepared by metalcatalyzed intramolecular photocyclizations of 1-aryl-3-(2-methoxy-1-naphthyl)- and 1-aryl-3-(1-methoxy-2-naphthyl)prop-2-en-1-ones.
机译:从邻硝基芳族醛制备1-芳基-3-(2-叠氮芳基)丙-2-烯-1-酮。从这些衍生物以串联反应顺序容易地以中等收率制备2-芳基吲哚衍生物。在这种转变中,发现光解过程比热过程更容易。萘并呋喃衍生物是通过对1-芳基-3-(2-甲氧基-1-萘基)-和1-芳基-3-(1-甲氧基-2-萘基)丙-2-烯-1-进行金属催化的分子内光环化反应制得的那些。

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