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首页> 外文期刊>Journal of the Indian Chemical Society >Furostan saponin and GOMS study toward ascertaining the point of linkage between sugars moieties of spirostan saponin from the rhizomes of Agapanthus africanus (Linn.)
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Furostan saponin and GOMS study toward ascertaining the point of linkage between sugars moieties of spirostan saponin from the rhizomes of Agapanthus africanus (Linn.)

机译：呋喃斯坦皂苷和GOMS的研究旨在确定非洲百子莲（Liaga。）的根茎中螺旋螺皂甙的糖部分之间的连接点。

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摘要

The linkage between the sugars moieties of antifungal spirostan saponin, (25R)-5α-spirost-7-en-2α,3β,5α-triol-3-O-{-O-α-L-rhamnopyranosyl-(1→2)-O-[β-D-galactopyranosyl-(1→3)]-β-D-glucopyranoside} of Agapanthus africanus (Linn.) have been determined by the analysis of GC-MS spectra of alditol acetates of the partially methylated sugars and the structures of the spirostan saponin and furostan saponin, 22-O-methyl-26-O-β-D-glucopyranosyl-(25R)-5α-furostan-2α,3p,5α,9α,22ζ,26-hexitol-3-O-{-O-α-L-rhamnopyranosyl-(1→2)-O-[β-D-galactopyranosyl-(1→3)]-β-D-glucopyranoside} isolated from the rhizomes of the A. africanus have been established by various spectral evidences. This is the first report of furostan saponin in A. africanus rhizomes as well as first account of the use of GC-MS technique to ascertain the linkage between the saccharide moieties of the active constituent of the plant.
机译：抗真菌螺旋螺皂甙，（25R）-5α-spirost-7-en-2α，3β，5α-三醇-3-O-{-O-α-L-鼠李糖吡喃糖基-（1→2）通过分析部分甲基化的糖的醛糖醇乙酸酯的GC-MS光谱和测定非洲百日草（Linn。）的-O- [β-D-吡喃半乳糖基-（1→3）]-β-D-吡喃葡萄糖苷}和螺旋藻皂苷和呋喃斯坦皂苷，22-O-甲基-26-O-β-D-吡喃吡喃糖基-（25R）-5α-呋喃斯坦-2α，3p，5α，9α，22ζ，26-己糖醇-3-的结构从非洲非洲根茎的根茎分离得到的O-{-O-α-L-鼠李糖基-（1→2）-O- [β-D-吡喃半乳糖基-（1→3）]-β-D-吡喃葡糖苷}由各种光谱证据确定。这是非洲非洲根茎中呋喃斯坦皂苷的首次报道，也是对使用GC-MS技术确定植物活性成分的糖部分之间联系的首次报道。

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