A mild and efficient method for the deoxygenation of #alpha#, #beta#-epoxyketones to enones

Kalyan Kumar Rana; Subhas Chandra Roy

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A mild and efficient method for the deoxygenation of #alpha#, #beta#-epoxyketones to enones

机译：温和有效的方法将＃alpha＃，＃beta＃-环氧酮脱氧为烯酮

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摘要

A mild and efficient method for the deoxygenation of #alpha#,#beta#-epoxyketones to the corresponding enones in excellent yield has been developed using a titanium(III) radical initiator. The deoxygenation occurred with complete loss of stereochemistry in the products.

机译：已经开发了使用钛（III）自由基引发剂的温和而有效的方法，以优异的产率将＃α＃，＃β＃-环氧酮脱氧为相应的烯酮。脱氧发生，产物中完全失去立体化学。

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《Journal of the Indian Chemical Society》 |1999年第12期|共2页
作者
Kalyan Kumar Rana; Subhas Chandra Roy;
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正文语种 eng
中图分类化学;
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1. A mild and efficient method for the deoxygenation of #alpha#, #beta#-epoxyketones to enones [J] . Kalyan Kumar Rana, Subhas Chandra Roy Journal of the Indian Chemical Society . 1999,第11a12期

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5. Mild lanthanide(III) catalyzed formation of trans-4,5-diaminocyclopent-2-enones and addition of potassium allyl- and crotyltrifluoroborates to imines. [D] . Li, Sze Wan. 2005

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A mild and efficient method for the deoxygenation of #alpha#, #beta#-epoxyketones to enones

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