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首页> 外文期刊>Journal of the Indian Chemical Society >Synthesis and characterization of Ni~(II), Cu~(II) and Zn~(II) complexes of N,O-mixed donor macrocycles derived from a-diketones and 1,13-diamino-4,7,10-trioxatridecane
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Synthesis and characterization of Ni~(II), Cu~(II) and Zn~(II) complexes of N,O-mixed donor macrocycles derived from a-diketones and 1,13-diamino-4,7,10-trioxatridecane

机译:衍生自α-二酮和1,13-二氨基-4,7,10-三氧杂环丁烷的N,O混合供体大环的Ni〜(II),Cu〜(II)和Zn〜(II)配合物的合成与表征

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摘要

Ni~(II), Cu~(II) and Zn~(II) complexes of the type [MLCl2] (M = Ni and Zn) and [CuL(NO3)2] (L = 17-membered N2O3 macrocycle) have been synthesized by [1 + 1] cyclocondensation of 1,13-diaminotrioxatridecane with α-diketones such as 2,3-butanedione, 2,3-pentanedione, 2,3-hexanedione and 3,4-hexanedione in the presence of Ni~(II), Cu~(II) and Zn~(II). These complexes have been characterized by elemental analyses, molar conductances, UV-Vis, IR, 'H NMR and FAB mass spectral studies.
机译:[MLCl2](M = Ni和Zn)和[CuL(NO3)2](L = 17元N2O3大环)类型的Ni〜(II),Cu〜(II)和Zn〜(II)配合物在Ni〜(1)存在下,由1,13-二氨基三氧杂环丁烷与2,3-丁二酮,2,3-戊二酮,2,3-己二酮和3,4-己二酮等α-二酮环缩合合成[1 +1]。 II),Cu〜(II)和Zn〜(II)。这些配合物的特征在于元素分析,摩尔电导,UV-Vis,IR,1 H NMR和FAB质谱研究。

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