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首页> 外文期刊>Journal of the Indian Chemical Society >Electroorganic synthesis of esters and ketones at the platinum anode in aqueous medium
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Electroorganic synthesis of esters and ketones at the platinum anode in aqueous medium

机译：水性介质中铂阳极上的有机合成酯和酮

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摘要

Electroorganic synthesis of esters from the saturated primary aliphatic alcohols and ketones from the secondary aliphatic alcohols have been carried out in electrooxidation at the platinum anode in aqueous medium. This is an important reaction because of high oxidation potential of alcohols. Electrochemical oxidation has been carried out under controlled potential electrolysis at room temperature in a three electrode cell assembly containing two platinum electrodes in the form of square plates as working as well as counter electrode and saturated calomel electrode was used as a reference electrode. The structures of compounds were confirmed from the IR, NMR, mass spectral and microanalyses. The products formed during the electrooxidation of ethanol, propanol, 1-butanol, 1-pentanol, 2-butanoi and sec-butyl alcohol are reported here.
机译：在含水介质中的铂阳极上，在电氧化反应中已经完成了从饱和伯脂肪族醇的酯的有机电合成和仲脂肪族醇的酮的有机电合成。由于醇的高氧化电位，这是重要的反应。在室温下，在三电极电池组件中，在受控电势电解下进行了电化学氧化，该组件包含两个以正方形板形式工作的铂电极以及对电极，饱和甘汞电极用作参比电极。化合物的结构由IR，NMR，质谱和显微分析证实。在此报道了乙醇，丙醇，1-丁醇，1-戊醇，2-丁醇和仲丁醇的电氧化过程中形成的产物。

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