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首页> 外文期刊>Journal of the Indian Chemical Society >Synthesis, characterization and biological properties of binuclear complexes of Cull, Ni-II and Co-II with 3,4-diphenyl-5-(2 '-hydroxyphenyl)-1,2,5-triazapenta-2,4-diene (DHTP)
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Synthesis, characterization and biological properties of binuclear complexes of Cull, Ni-II and Co-II with 3,4-diphenyl-5-(2 '-hydroxyphenyl)-1,2,5-triazapenta-2,4-diene (DHTP)

机译：Cull，Ni-II和Co-II与3,4-二苯基-5-（2'-羟苯基）-1,2,5-三氮杂戊2,4-二烯（DHTP）的双核配合物的合成，表征和生物学性质）

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摘要

The synthesis and characterization of a series of homo binuclear metal complexes of Cu-II, Ni-II and Co-II with the titled ligand 3,4-dipheny1-5-(2'-hydroxypheny0-1,2,5-triazapenta-2,4-diene (DHTP) have been reported. The complexes have been synthesized by treating an ethanolic solution of the ligand with equimolar amount of appropriate metal salts in ethanol by a direct route and also by template synthesis using in situ method. The ligand and its metal complexes have been characterized on the basis of analytical and spectral data, thermal analysis, magnetic and conductivity measurements. Based on the results, tentative structures of the complexes have been proposed. The ligand as well as the metal complexes exhibit antimicrobial activities against the pathogenic fungus Aspergillus lager, Helminthosporiuin oryzae and Fusarium oxysporium. The fungicidal activities of the complexes have been compared with a standard fungicide Fluconazole.
机译：一系列具有标题配体3,4-dipheny1-5-（（2'-hydroxypheny0-1,2,5-triazapenta--）的Cu-II，Ni-II和Co-II均双核金属配合物的合成和表征已经报道了2，4-二烯（DHTP），通过用等摩尔量的适当金属盐在乙醇中的配体的乙醇溶液通过直接途径并通过原位方法通过模板合成来合成配合物。在分析和光谱数据，热分析，磁和电导率测量的基础上对其金属配合物进行了表征，并据此提出了配合物的暂定结构，其配体以及金属配合物均具有抗微生物活性。病原性真菌为曲霉菌，稻瘟病菌（Helminthosporiuin oryzae）和尖孢镰刀菌（Fusarium oxysporium），并与标准杀真菌剂氟康唑进行了比较。

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