ELECTROCHEMICAL SYNTHESIS OF BIS(2-THIENYL)SILANES, 2-THIENYLCHLOROSILANES, BIS[5-(2-BROMOTHIENYL)]SILANES, AND 5-(2-BROMOTHIENYL) DIMETHYLCHLOROSILANE, PRECURSORS OF POLY[(SILANYLENE)THIOPHENE]S

Moreau C.; Bordeau M.; Biran C.; Dunogues J.; Sereinspirau F.

首页> 外文期刊>Journal of Organometallic Chemistry >ELECTROCHEMICAL SYNTHESIS OF BIS(2-THIENYL)SILANES, 2-THIENYLCHLOROSILANES, BIS[5-(2-BROMOTHIENYL)]SILANES, AND 5-(2-BROMOTHIENYL) DIMETHYLCHLOROSILANE, PRECURSORS OF POLY[(SILANYLENE)THIOPHENE]S

【24h】

ELECTROCHEMICAL SYNTHESIS OF BIS(2-THIENYL)SILANES, 2-THIENYLCHLOROSILANES, BIS[5-(2-BROMOTHIENYL)]SILANES, AND 5-(2-BROMOTHIENYL) DIMETHYLCHLOROSILANE, PRECURSORS OF POLY[(SILANYLENE)THIOPHENE]S

机译：电化学合成双（2-噻吩基）硅酮，2-噻吩基氯硅烷，双[5-（2-溴代苯基）]硅酮和5-（2-溴代苯基）二甲基氯硅烷，聚[（硅烷基）噻吩]的前体

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Bis(2-thienyl)silanes and bis[5-(2-bromothienyl)]silanes were synthesized by electrochemical reduction of monohalothiophenes (Br,CI) and 2,5-dibromothiophene respectively in the presence of a dichlorosilane in THF or DME, using an undivided cell, a sacrificial Mg or Al anode, a constant current density and tetrabutylammonium bromide as the supporting electrolyte. In addition, when dichlorosilanes were used in large excess, halothiophenes underwent solely a monocoupling reaction leading selectively to thienylchlorosilanes, which reveals the versatility of the electrochemical method. [References: 29]

机译：在THF或DME中，在二氯硅烷存在下，分别通过电化学还原单卤代噻吩（Br，Cl）和2,5-二溴噻吩，合成了双（2-噻吩基）硅烷和双[5-（2-溴噻吩基）]硅烷。一个未分割的电池，一个牺牲性的Mg或Al阳极，一个恒定的电流密度和四丁基溴化铵作为支持电解质。另外，当大量使用二氯硅烷时，卤代噻吩仅进行单偶联反应，选择性地导致噻吩基氯硅烷，这揭示了电化学方法的多功能性。 [参考：29]

著录项

来源
《Journal of Organometallic Chemistry》 |1996年第2期|共9页
作者
Moreau C.; Bordeau M.; Biran C.; Dunogues J.; Sereinspirau F.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
Silicon; Thienylsilanes; Synthesis; Electrochemical synthesis; Poly(silanylene)thiophene precursors; Halide; Polymeric organosilicon systems; Thiophene; Polythiophene; Electropolymerization; Trimethylsilylation; Copolymers; Units; Route;

机译：硅;噻吩硅烷;合成;电化学合成;聚[（（亚硅烷基）噻吩]前体;卤化物;聚合物有机硅体系;噻吩;聚噻吩;电聚合;三甲基硅烷化;共聚物;单元;路线;

相似文献

外文文献
中文文献
专利

1. ELECTROCHEMICAL SYNTHESIS OF BIS(2-THIENYL)SILANES, 2-THIENYLCHLOROSILANES, BIS[5-(2-BROMOTHIENYL)]SILANES, AND 5-(2-BROMOTHIENYL) DIMETHYLCHLOROSILANE, PRECURSORS OF POLY[(SILANYLENE)THIOPHENE]S [J] . Moreau C., Bordeau M., Biran C., Journal of Organometallic Chemistry . 1996,第2期

机译：电化学合成双（2-噻吩基）硅酮，2-噻吩基氯硅烷，双[5-（2-溴代苯基）]硅酮和5-（2-溴代苯基）二甲基氯硅烷，聚[（硅烷基）噻吩]的前体
2. Synthesis of Some New bis-(p-Fluorophenyl)amides of the Thieno[3,2-b]thiophene, Thieno[3,2-b]furan and 1,2-bis{5-[2-(2-Thienyl)ethenyl]2-thienyl}ethene Series [J] . Grace Karminski-Zamola Molecules . 2002,第12期

机译：噻吩并[3,2-b]噻吩，噻吩并[3,2-b]呋喃和1,2-双{5- [2- [2-噻吩基]]的一些新的双-（对氟苯基）酰胺的合成乙烯基] 2-噻吩基}乙烯基系列
3. SILICON-CONTAINING AROMATIC POLY(ESTERS) DERIVED FROM BIS(4-CARBOXYPHENYL)METHYL-R-SILANE AND BIS(4-(HYDROXYMETHYL) PHENYL)METHYL-R-SILANE: SYNTHESIS, CHARACTERIZATION AND THERMAL STUDIES [J] . TAGLE LUISH, TERRAZA CLAUDIO A, PINO LEONARDO I Journal of the Chilean Chemical Society . 2012,第2期

机译：双（4-羧苯基）甲基-R-硅烷和双（4-（羟甲基）苯基）甲基-R-硅烷衍生的含硅芳香族聚酯：合成，表征和热学研究
4. ELECTROCHEMICAL AND QUANTUM CHEMICAL STUDIES OF 2,5- BIS(N-PYRIDYL)-1,2,4-OXADIAZOLES AS CORROSION INHIBITORS FOR CARBON STEEL IN 1 M HCL SOLUTION [C] . Michel LAGRENEE, Moha OUTIRITE, Herve VEZIN, European corrosion congress;EUROCORR 2009 . 2009

机译：1,5-BIS（N-吡啶基）-1,2,4-恶二唑在1 M HCL溶液中对碳钢的腐蚀抑制剂的电化学和量子化学研究
5. The synthesis of a new polymeric ligand poly[5-(1,3-bis-(2'-pyridylimino)isoindolyloxy)ethylene] (PBPIIIOE) [D] . Jiang, Yi. 2000

机译：新型聚合物配体聚[5-（1,3-双-（2'-吡啶基氨基）异吲哚基氧基）乙烯]（PBPIIIOE）的合成
6. Polyμ5-{hydrogen bis(E)-cinnamato}-caesium [O] . Graham Smith 2014

机译：聚μ5-{氢双（E）-肉桂）-铯
7. Synthesis of Some New bis-(p-Fluorophenyl)amides of the Thieno[3,2-b]thiophene, Thieno[3,2-b]furan and 1,2-bis{5-[2-(2-Thienyl)ethenyl]2-thienyl}ethene Series [O] . Grace Karminski-Zamola, Zrinka Banic-TomiÃ…Â¡ic, Jasna Dogan KoruÃ…Â¾njak, 2002

机译：一些新的噻吩并[3,2-b]噻吩，噻吩并[3,2-b]呋喃和1,2-双{5- [2-（2-噻吩基））的双 - （对氟苯基）酰胺的合成乙烯基] 2-噻吩基}乙烯系列

ELECTROCHEMICAL SYNTHESIS OF BIS(2-THIENYL)SILANES, 2-THIENYLCHLOROSILANES, BIS[5-(2-BROMOTHIENYL)]SILANES, AND 5-(2-BROMOTHIENYL) DIMETHYLCHLOROSILANE, PRECURSORS OF POLY[(SILANYLENE)THIOPHENE]S

摘要

著录项

相似文献

相关主题

期刊订阅