Dimers of highly pi-loaded organoimido d(1) metal radicals of niobium, tantalum, molybdenum, tungsten, and rhenium: the context of the cyclopentadienyl imido ligand analogy

Radius U.; Schorm A.; Kairies D.; Schmidt S.; Moller F.; Pritzkow H. Sundermeyer J.

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Dimers of highly pi-loaded organoimido d(1) metal radicals of niobium, tantalum, molybdenum, tungsten, and rhenium: the context of the cyclopentadienyl imido ligand analogy

机译：铌，钽，钼，钨和rh的高pi负载有机亚氨基d（1）金属自由基的二聚体：环戊二烯基亚氨基配体的类比

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The reductive generation and dimerisation of highly pi-loaded and coordinatively unsaturated d(1) imido metal radicals of the type [Cp2M(NR)] (M = Nb, Ta), [CpM(NR)(2)] (M = Mo, W), and [Re(NR)(3)] is described. Their dinuclear spin-coupled complexes are characterized by crystal structure determinations and their bonding situation is discussed with reference to the cyclopentadienyl imido ligand analogy. (C) 2002 Elsevier Science B.V. All rights reserved. [References: 43]

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《Journal of Organometallic Chemistry》 |2002年第2期|共9页
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Radius U.; Schorm A.; Kairies D.; Schmidt S.; Moller F.; Pritzkow H. Sundermeyer J.;
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中图分类有机化学;
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1. Dimers of highly pi-loaded organoimido d(1) metal radicals of niobium, tantalum, molybdenum, tungsten, and rhenium: the context of the cyclopentadienyl imido ligand analogy [J] . Radius U., Schorm A., Kairies D., Journal of Organometallic Chemistry . 2002,第1a2期

机译：铌，钽，钼，钨和rh的高pi负载有机亚氨基d（1）金属自由基的二聚体：环戊二烯基亚氨基配体的类比
2. Half-sandwich dichloro, alkyl chloro, dialkyl, alkyl methyl and amido methyl imido cyclopentadienyl niobium and tantalum(V) complexes. Dynamic behaviour of amido imido tantalum derivatives [J] . Aurora Castro, Mikhail V. Galakhov, Manuel Gomez, Journal of Organometallic Chemistry . 1999,第1期

机译：半三明治二氯，烷基氯，二烷基，烷基甲基和酰胺基甲基亚氨基环戊二烯基铌和钽（V）配合物。酰胺基亚胺基钽衍生物的动力学行为
3. Combined Electrochemical Processing of the Wastes of Nickel Superalloys Containing Rhenium, Tungsten, Tantalum, Niobium, and Other Precious Metals [J] . A. A. Palant, V. A. Bryukvin, A. M. Levin Russian Metallurgy(Metally) . 2014,第1期

机译：含R，钨，钽，铌和其他贵金属的镍超合金废料的联合电化学处理
4. Inorganic Models for Two-Electron Redox Chemistry in Biological Systems Ligand-Bridged Molybdenum and Tungsten Dimers [C] . Annual meeting of the ACS Central Region . 2009

机译：生物系统中双电子氧化还原化学的无机模型配体 - 桥接钼和钨二聚体
5. SYNTHESIS AND CHEMISTRY OF CARBONYLMETALLATE TRIANIONS OF VANADIUM, NIOBIUM, TANTALUM, MANGANESE, RHENIUM, COBALT AND IRIDIUM. PART ONE: THE CHEMISTRY OF THE PENTACARBONYLMETALLATE TRIANIONS OF VANADIUM, NIOBIUM AND TANTALUM. PART TWO: THE CHEMISTRY OF THE TETRACARBONYLMETALLATE TRIANIONS OF MANGANESE AND RHENIUM. PART THREE: THE CHEMISTRY OF THE TRICARBONYLMETALLATE TRIANIONS OF COBALT AND IRIDIUM. [D] . WARNOCK, GARRY FRANCIS. 1985

机译：钒，铌，钽，锰、,、钴和铱的羧甲基三羧酸三嗪的合成与化学性质。第一部分：钒，铌和钽的五甲基戊酸三苯酯的化学性质。第二部分：锰和HEN的四甲基甲磺酸三苯醚的化学性质。第三部分：钴和铱的三氟甲磺酸三苯并三酯的化学性质。
6. A study of some metal cluster systems containing niobium, tantalum, molybdenum and tungsten [O] . Dorman, William Clifford 1974

机译：对一些包含铌，钽，钼和钨的金属簇系统的研究

Dimers of highly pi-loaded organoimido d(1) metal radicals of niobium, tantalum, molybdenum, tungsten, and rhenium: the context of the cyclopentadienyl imido ligand analogy

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