Transition Metal Promoted Oxidative C-N Fusion Reactions of Aromatic Amines and Their Coordination Chemistry

Chayan Das; Sreebrata Goswami

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Transition Metal Promoted Oxidative C-N Fusion Reactions of Aromatic Amines and Their Coordination Chemistry

机译：过渡金属促进的芳香胺氧化C-N融合反应及其配位化学

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Some unusual examples of metal promoted oxidative dimerization and polymerization, via C-N bond formation, of aromatic mono- as well as di-amines are described. Successful isolation and thorough characterization of the products follow these reactions. Electrochemical and spectral studies of the complexes are reported and compared with related systems. While the heavier transition metal ions like ruthenium(III) and osmium(IV) mediate ortho-dimerization of primary amines, ArNH_2, Fe(III), on the other hand, promotes polymerization. Similar fusion reaction of 1, 3-diami-nobenzene with the mediator complex, [Ru(acac)_3] (acac = acetyl acetonate), led to the formation of diruthenium complexes.

机译：描述了一些不寻常的例子，这些例子是金属通过C-N键形成的芳族单胺和二胺促进了氧化二聚和聚合反应。这些反应会成功分离出产品并对其进行全面表征。报告了配合物的电化学和光谱研究，并与相关系统进行了比较。较重的过渡金属离子（如钌（III）和（IV））介导伯胺的原二聚，而ArNH_2，Fe（III）则促进聚合。 1，3-二亚氨基苯与介质配合物[Ru（acac）_3]（acac =乙酰丙酮酸）的相似融合反应导致形成二钌配合物。

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《Comments on Inorganic Chemistry: A Journal of Critical Discussion of the Current Literature》 |2003年第4期|共27页
作者
Chayan Das; Sreebrata Goswami;
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正文语种 eng
中图分类有机化学;
关键词
metal-mediation; organic transformation; metal-diimines; X-ray structures; redox;

机译：金属中介;有机相变;金属二亚胺;X射线结构;氧化还原;

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1. Transition Metal Promoted Oxidative C-N Fusion Reactions of Aromatic Amines and Their Coordination Chemistry [J] . Chayan Das, Sreebrata Goswami Comments on Inorganic Chemistry: A Journal of Critical Discussion of the Current Literature . 2003,第3a4期

机译：过渡金属促进的芳香胺氧化C-N融合反应及其配位化学
2. Metal-assisted reactions. Part 29.~1 Structure and hydrogenolysis of C-N bonds in derivatives of aromatic amines. Bond length and electronegativity changes from X-ray crystallographic data [J] . Amadeu F. Brigas, William Clegg, Christopher J. Dillon, Journal of the Chemical Society. Perkin Transactions 2 . 2001,第8期

机译：金属辅助反应。第29.〜1部分：芳族胺衍生物中C-N键的结构和氢解作用。 X射线晶体学数据的键长和电负性变化
3. Design and synthesis of a new binucleating ligand via cobalt-promoted C-N bond fusion reaction. Ligand isolation and its coordination to nickel, palladium, and platinum [J] . Kamar KK., Das S., Hung CH., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2003,第17期

机译：通过钴促进的C-N键融合反应设计和合成新的双核配体。配体隔离及其与镍，钯和铂的配位
4. Metallosilicate mesoporous catalysts prepared by incorporation of transition metals in the MCM-41 molecular sieves and their catalytic activity in selective oxidation of aromatics (styrene and benzene) [C] . V. Parvulescu, B. L. Su 8th International Symposium on Scientific Bases for the Preparation of Heterogeneous Catalysts, Sep 9-12, 2002, Louvain-la-Neuve, Belgium . 2002

机译：通过在MCM-41分子筛中掺入过渡金属制备的金属硅酸盐介孔催化剂及其在芳烃（苯乙烯和苯）的选择性氧化中的催化活性
5. The Coordination Chemistry of the Janus-head Ligand Tris(2-pyridyl)phosphine and Its Oxide with Nitrates of Divalent Late First Row Transition Metals and Trivalent Lanthanides. [D] . Pericic, Danijel Josip. 2014

机译：Janus头配体三（2-吡啶基）膦及其氧化物与二价晚排第一过渡金属和三价镧系元素的硝酸盐的配位化学。
6. Applications of Bis(1-R-imidazol-2-yl)disulfides and Diselenides as Ligands for Main Group and Transition Metals: κ2-NN Coordination S-S Bond Cleavage and S-S/E-E (E = S Se) Bond Metathesis Reactions [O] . Joshua S. Figueroa, Kevin Yurkerwich, Jonathan Melnick, -1

机译：双（1-R-咪唑-2-基）二硫化物和二硒化物作为主族和过渡金属的配体的应用：κ2-NN配位SS键断裂和SS / EE（E = SSe）键复分解反应
7. Design and synthesis of multidentate ligands via metal promoted C-N bond formation processes and their coordination chemistry [O] . Kunal K Kamar, Amrita Saha, Sreebrata Goswami 2002

机译：金属促进C-N键形成过程的多型配体的设计与合成及其协调化学
8. Transition Metal-Promoted Oxidative Fusion with Carborane and Borane Anions. Synthesis of C4Bn (N = 8-11) Carborane Systems in the Presence of B5H8- or B3H8- Ions [R] . Hosmane, N. S., Grimes, R. N. 1980

机译：过渡金属促进氧化融合与碳硼烷和硼烷阴离子。在B5H8-或B3H8-离子存在下合成C4Bn（N = 8-11）碳硼烷体系

Transition Metal Promoted Oxidative C-N Fusion Reactions of Aromatic Amines and Their Coordination Chemistry

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