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Solid-State Materials and Molecular Cavities and Containers for the Supramolecular Recognition and Storage of NOX-Species: A Review

机译:固态材料和分子腔以及用于NOX物种超分子识别和储存的容器:综述

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Solid-state materials, such as small-cavity zeolites, carbon and boron nitride nanotubes, etc., as well as organic molecular cavities and containers, such as calix-, resorcin-, pillar[n]arenes, etc., offer great potential for their applications for the selective optical and/or electrochemical detection, extraction and storage (via encapsulation) of NOx species (N2O, NO, NO2/N2O4, etc.), among others (O-2, CO2, SOx, etc.). This is of great importance, since NOx species are known as environmental pollutants and physiologically active compounds. This review is focused on the recent advances on the detection and effective storage of NOx gases with the employment of both organic molecular cavities and containers and inorganic solid-state materials. The effects of structural variations, including the NOx recognition mode, type of the material (inorganic or organic), geometric sizes, and conformation variations, are discussed.
机译:固态材料(例如小腔沸石,碳和氮化硼纳米管等)以及有机分子腔和容器(例如杯形,间苯二酚,立柱芳烃等)具有巨大的潜力应用于选择性光学和/或电化学检测,提取和储存(通过封装)NOx物质(N2O,NO,NO2 / N2O4等),以及其他(O-2,CO2,SOx等) 。这非常重要,因为NOx物种被称为环境污染物和生理活性化合物。这篇综述的重点是利用有机分子腔和容器以及无机固态材料来检测和有效存储NOx气体的最新进展。讨论了结构变化的影响,包括NOx识别模式,材料类型(无机或有机),几何尺寸和构象变化。

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