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Interaction of a Porous Carbon Particle with Steam and Carbon Dioxide

机译:多孔碳颗粒与蒸汽和二氧化碳的相互作用

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As part of a diffusion-kinetic model of gasification of a porous carbon particle in steam and carbon dioxide, this paper presents a study of heat- and mass-transfer processes both inside the porous particle and in the gas phase above its surface. The radiation heat transfer between the particle and the walls of the furnace is taken into account. Heterogeneous reactions of carbon with steam and carbon dioxide and the homogeneous reaction of carbon monoxide with steam, are considered. In addition, allowance is made for pressure variation in the porous particle due to an increase in gas mass during heterogeneous reactions. Dependences of the gasification rate on the composition of the reaction mixture, pressure, furnace temperature, and particle size, and the inner surface area of the porous carbon particle.
机译:作为蒸汽和二氧化碳中多孔碳颗粒气化扩散动力学模型的一部分,本文提出了对多孔颗粒内部以及其表面上方气相的传热和传质过程的研究。考虑了颗粒与炉壁之间的辐射热传递。考虑了碳与蒸汽和二氧化碳的非均相反应以及一氧化碳与蒸汽的均相反应。另外,由于在非均相反应期间气体质量的增加而允许多孔颗粒中的压力变化。气化速率取决于反应混合物的组成,压力,炉温和粒度以及多孔碳颗粒的内表面积。

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