The Domino Chemistry Approach to Molecular Complexity:Competing Domino Processes Modulated by the Substitution Pattern

Imad Safir; Isabel Castellote; Susana Porcel

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The Domino Chemistry Approach to Molecular Complexity:Competing Domino Processes Modulated by the Substitution Pattern

机译：用于分子复杂性的多米诺化学方法：竞争模式替代模式调制的多米诺过程

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Oxidative cleavage with lead tetraacetate results in the synthesis of different oxygen heterocycles starting from the same unsaturated 1,2-diol of type I by tuning of the substitution pattern at the angular position.When this compound bears a functional substituent,such as an alkoxy,ester,alkenyl,or simply a hydrogen,more than one reaction pathway are in competition.The process allows for the selective formation of three different complex ring systems,by the appropriate choice of the angular substituent,leading to either a ring-expanded type 1,ring-retained type 2,or domino products 3.

机译：用四乙酸铅氧化裂解可通过调节角位置的取代方式从相同的I型不饱和1,2-二醇开始合成不同的氧杂环。当该化合物带有功能性取代基（如烷氧基）时，酯，链烯基，或者简单地为氢，多于一个的反应途径是在竞争。过程允许三个不同的复杂的环系的选择性形成，由角度取代基的合适的选择，从而导致无论是环扩展型1 ，固定环2型或多米诺骨牌产品3。

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《Chemistry: A European journal》 |2006年第28期|共8页
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Imad Safir; Isabel Castellote; Susana Porcel;
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cyclic oxoniums domino reactions;

机译：环氧鎓多米诺骨牌反应;

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1. The Domino Chemistry Approach to Molecular Complexity:Competing Domino Processes Modulated by the Substitution Pattern [J] . Imad Safir, Isabel Castellote, Susana Porcel Chemistry: A European journal . 2006,第28期

机译：用于分子复杂性的多米诺化学方法：竞争模式替代模式调制的多米诺过程
2. The domino chemistry approach to molecular complexity: high-yielding bis-hetero intramolecular Diels-Alder reactions with ketone components [J] . Chanu A, Castellote I, Commeureuc A, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2006,第17期

机译：用多米诺化学方法解决分子复杂性：酮类成分的高产双-异分子内Diels-Alder反应
3. Mild Protocols for Generating Molecular Complexity:A Comparative Study of Hetero-Domino Reactions Based on the Oxidant and the Substitution Pattern [J] . Jose I.Candela Lena, Elena M.Sanchez Fernandez, Alwar Ramani, European journal of organic chemistry . 2005,第4期

机译：产生分子复杂性的温和方案：基于氧化剂和取代模式的异多米诺反应的比较研究
4. Two-by-Two Substitution Systems and the Undecidability of the Domino Problem [C] . Nicolas Ollinger Logic and Theory of Algorithms . 2008

机译：两乘二替补制与多米诺骨牌问题的不确定性
5. Rhodium-dicarbon monoxide-chloride-catalyzed allylic substitution reactions and domino sequences and application of the Pauson-Khand reaction to the synthesis of azabicyclic structures: Total synthesis of (-)-alstonerine [D] . Miller, Kenneth Aaron 2007

机译：铑-一氧化碳-氯化物催化的烯丙基取代反应和多米诺骨牌序列以及Pauson-Khand反应在氮杂双环结构合成中的应用：（-）-alstonerine的总合成
6. Allylic Amination and N-Arylation-Based Domino Reactions Providing Rapid Three-Component Strategies to Fused Pyrroles with Different Substituted Patterns [O] . Bo Jiang, Ying Li, Man-Su Tu, -1

机译：烯丙基胺化和基于N-芳基化的多聚骨的反应提供快速的三分组分策略以具有不同取代的图案的熔化烟草
7. Beyond simple proton transfer processes: domino reactions between 4-substituted indoles and nitroethene as a new gateway to ergot alkaloids [O] . Romanini Simone 2014

机译：超越简单的质子转移过程：4-取代的吲哚与硝基乙烯之间的多米诺反应作为麦角生物碱的新途径

The Domino Chemistry Approach to Molecular Complexity:Competing Domino Processes Modulated by the Substitution Pattern

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