Sodium Cation Migration Above the Diimine pi-System of Solvent Coordinated dpp-BIAN Sodium Aluminum Complexes(dpp-BIAN=1,2-Bis[(2,6-diisopropylphenyl)imino]acenaphthene)

Herbert Schumann; Markus Hummert; Anton N.Lukoyanov

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Sodium Cation Migration Above the Diimine pi-System of Solvent Coordinated dpp-BIAN Sodium Aluminum Complexes(dpp-BIAN=1,2-Bis[(2,6-diisopropylphenyl)imino]acenaphthene)

机译：溶剂配位的dpp-BIAN铝铝配合物（dpp-BIAN = 1,2-Bis [（2,6-二异丙基苯基）亚氨基] ac的二亚胺pi-体系上的钠阳离子迁移

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The reactions of the disodi- um salt of the 1,2-bis[(2,6-diisopropyl- phenyl)imino]acenaphthene (dpp-BIAN)ligand with one equivalent of Me2AlCl in diethyl ether,toluene,and benzene produced the complexes[Na-(Et2O)2(dpp-BIAN)AlMe2](1),[Na(eta6-C7H8)(dpp-BIAN)AlMe2](2)and[Na-(eta6-C6H6)(dpp-BIAN)AlMe2](3),re spectively.Recrystallization of 1 from hexane afforded solvent-free[{Na(dpp-BIAN)AlMe2}_n](4)or[Na(Et2O)(dpp-BIAN)AlMe2](5)depending on the temperature of the solvent.The molec ular structures of 1-5 have been deter-mined by single-crystal X-ray diffrac tion.The sodium cation coordinates either one of the naphthalene rings(1)or the diimine part of the dpp-BIAN ligand(2-5).In the complexes 2 and 3,the sodium cation additionally coordi nates the toluene(2)or benzene mole cule(3)in an eta6-fashion.

机译：1,2-双[（2,6-二异丙基-苯基）亚氨基] ac烯（dpp-BIAN）配体的二盐与一当量的Me2AlCl在乙醚，甲苯和苯中的反应生成了络合物[Na-（Et2O）2（dpp-BIAN）AlMe2]（1），[Na（eta6-C7H8）（dpp-BIAN）AlMe2]（2）和[Na-（eta6-C6H6）（dpp-BIAN）AlMe2 ]（3）。从己烷中重结晶1可得到无溶剂的[{Na（dpp-BIAN）AlMe2} _n]（4）或[Na（Et2O）（dpp-BIAN）AlMe2]（5），具体取决于通过单晶X射线衍射确定1-5的分子结构。钠阳离子配位于萘环（1）之一或dpp-的二亚胺部分BIAN配体（2-5）。在配合物2和3中，钠阳离子还会以eta6-方式配合甲苯（2）或苯分子（3）。

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《Chemistry: A European journal》 |2007年第15期|共7页
作者
Herbert Schumann; Markus Hummert; Anton N.Lukoyanov;
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正文语种 eng
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arenes; main group ele ments; N ligands; pi interactions; sodium;

机译：芳烃;主族元素;N配体;π相互作用;钠;

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1. Sodium Cation Migration Above the Diimine pi-System of Solvent Coordinated dpp-BIAN Sodium Aluminum Complexes(dpp-BIAN=1,2-Bis[(2,6-diisopropylphenyl)imino]acenaphthene) [J] . Herbert Schumann, Markus Hummert, Anton N.Lukoyanov Chemistry: A European journal . 2007,第15期

机译：溶剂配位的dpp-BIAN铝铝配合物（dpp-BIAN = 1,2-Bis [（2,6-二异丙基苯基）亚氨基] ac的二亚胺pi-体系上的钠阳离子迁移
2. Alkylmagnesium complexes with the rigid dpp-bian ligand {dpp-bian 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene} [J] . Fedushkin IL, Morozov AG, Hummert M, European journal of inorganic chemistry . 2008,第10期

机译：具有刚性dpp-bian配体的{{dpp-bian 1,2-双[（2,6-二异丙基苯基）亚氨基] ac]烷基镁配合物
3. Alkylmagnesium complexes with the rigid dpp-bian ligand {dpp-bian 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene} [J] . Fedushkin IL, Morozov AG, Hummert M, European journal of inorganic chemistry . 2008,第10期

机译：具有刚性dpp-bian配体的{{dpp-bian 1,2-双[（2,6-二异丙基苯基）亚氨基] ac]烷基镁配合物
4. RING-OPENING METATHESIS ACTIVITY OF RUTHENIUM-BASED OLEFIN METATHESIS CATALYST COORDINATED WITH 1,3-BIS(2,6-DIISOPROPYLPHENYL)-4,5-DIHYDROIMIDAZOLINE [C] . SOLMAZ KARABULUT, FRANCIS VERPOORT NATO Advanced Study Institute on Metathesis Chemistry: From Nanostructure Design to Synthesis of Advanced Materials . 2007

机译：钌基烯烃复分解催化剂的开环复分解活性配位1,3-双（2,6-二异丙基苯基）-4,5-二氢咪唑啉
5. Two-Electron Carbon Dioxide Reduction Catalyzed by Rhenium(I) Bis(imino)acenaphthene Carbonyl Complexes [O] . Engelbert Portenkirchner, Elham Kianfar, Niyazi Serdar Sariciftci, -1

机译：hen（I）双（亚氨基）ac烯羰基配合物催化的双电子二氧化碳还原
6. Divalent Germanium Compound with a Radical-Anionic Ligand: Molecular Structures of (dpp-BIAN)-GeCl and Its Hydrochloration Products (dpp-BIAN)(H)2+GeCl3- and {(dpp-BIAN)(H)2+}2(Cl-)+GeCl3- (dpp-BIAN = 1, 2-Bis{(2, 6-diisopropylphenyl)imino}acenaphthene) [O] . -1

机译：具有自由基阴离子配体的二价锗化合物：（DPP-BIAN）-GECL的分子结构及其氢氯化产物（DPP-BIAN）（H）2 + GECL3-和{（DPP-BIAN）（H）2+} 2 （Cl - ）+ GECL3-（DPP-Bian = 1,2-双{（2,6-二异丙基苯基）亚氨基}亚苯甲酸根）

Sodium Cation Migration Above the Diimine pi-System of Solvent Coordinated dpp-BIAN Sodium Aluminum Complexes(dpp-BIAN=1,2-Bis[(2,6-diisopropylphenyl)imino]acenaphthene)

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